The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The most important characteristics of a fireclay are that it shall be
able to resist any temperature to which it may be exposed and that the
articles into which it is made shall not be affected by rapid changes in
temperature. Other characteristics of importance in some industries are
the resistance to corrosive action of slags and vapours, to cutting and
abrasion by dust in flue-gases or by the implements used in cleaning the
fires. For those purposes it is necessary that a fireclay should possess
high infusibility (p. 32), a low burning shrinkage (p. 29) and a high
degree of refractoriness (p. 34), and before it is used these
characteristics should be ascertained by means of definite tests, as
they cannot be determined by inspection of a sample or from a study of
its chemical analysis.
Several grades of fireclay have long been recognized on the Continent
and in the United States of America, but the recent Specification of the
Institution of Gas Engineers is the only official recognition in Great
Britain of definite grades. This specification defines as No. 1 grade a
fireclay which shows no signs of fusion when heated to 1670° C. or Cone
30 at the rate of 10° C. per minute, and as No. 2 grade fireclay those
which show no signs of fusion when similarly heated to 1580° C. or Cone
26.
It is regarded as a sign of fusion if a test piece with sharp angles
loses its angularity after heating to a predetermined temperature (see
p. 35).
It is customary to regard as 'fireclay' all clays which, when formed
into the shape of a Seger Cone (fig. 6) do not bend on heating slowly
until a temperature of 1580° C. (Cone 26) is reached. Any clays
comprised within this definition and yet not sufficiently refractory to
be of the No. 2 grade just mentioned may be regarded as No. 3 grade
fireclays. Many of the last named are well suited for the manufacture of
blocks for domestic fireplaces, for glazed bricks and for firebricks not
intended to resist furnace temperatures.
To resist sudden changes in temperature the material must be very
porous--the article being capable of absorbing at least one-sixth of its
volume of water. For this reason it is customary to mix fireclays with a
large proportion of non-plastic material of a somewhat coarse texture,
the substance most generally employed being fireclay which has been
previously burned and then crushed. This material is known as _grog_ or
_chamotte_ and has the advantage over other substances of not affecting
the composition of the fireclay to which it is added, whilst greatly
increasing its technical usefulness. The addition of grog also reduces
the shrinkage of the clay during drying and ensures a sounder article
being produced.
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