The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
As the china clays (kaolins) and ball clays on very careful elutriation
all yield a product of the same ultimate composition, viz. 39 per cent.
of alumina, 46 per cent. of silica, 13 per cent. of water, and 2 per
cent. of other oxides, they are generally regarded as consisting of
practically pure clay with a variable amount of impurities. Many years
ago Fresenius suggested that these non-clayey constituents of clays
should be calculated into the minerals to which they appeared likely to
correspond so as to obtain a result similar to that obtained by Seger
without the disadvantages of the treatment with sulphuric acid and as
supplementary to such treatment in the case of red-burning and some
other clays. More recent investigators have found that if a careful
microscopic examination of the clay is made the results of estimating
the composition from the proportion of the different minerals
recognizable under the microscope and by calculation from the analysis
of the material agree very closely and are, as Bischof (28) and, more
recently, Mellor have pointed out, more reliable than the 'rational
analysis' in the case of impure clays. If care is taken to make a
microscopical examination identifying the chief impurities present the
calculation from the analysis may usually be accepted as sufficiently
accurate, but it is very unsatisfactory to assume, as some chemists do,
that the alkalies and lime in the clay are all in the form of felspar
and that the silica remaining in excess of that required to combine with
the alkalies, lime and alumina is free quartz. Some clays are almost
destitute of felspar but comparatively rich in mica, whilst others are
the reverse, so that some means of identifying the extraneous minerals
is essential. When this is not used, the curious result is obtained
that German chemists calculate the alkalies, etc. to felspar whilst the
French chemists, following Vogt, calculate them to mica; English ceramic
chemists appear undecided as to which course to follow, and some of them
occasionally report notable amounts of felspar in clays quite destitute
of this mineral!
A statement of the composition of a 'clay' based on a mechanical
separation of the coarser ingredients followed by an analysis of the
finer ones and a calculation of the probable constituents of the latter,
as already described, is known as a _proximate analysis_ in order to
distinguish it from an _ultimate analysis_ which states the composition
of the whole material in terms of its ultimate oxides. A proximate
analysis therefore shows the various materials entering into the
composition of the clay in the following or similar terms:
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