The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Stones per cent.
Gravel "
Coarse sand "
Medium sand "
Fine sand "
Silt "
Felspar or mica dust "
Silica dust "
'True clay[12]' "
Moisture "
Carbon "
Other volatile matter "
[Footnote 12: In analytical reports a note should be appended stating
that the figure under this term shows the proportion of the nearest
approximation to true clay at present attainable.]
For some purposes it is necessary to show the proportion of calcium,
iron and other compounds as in an ordinary ultimate analysis.
A comparison of the foregoing with an ultimate or 'ordinary' analysis of
a clay (p. 16) will show at once the advantage of the former in
increasing our knowledge of the essential constituent of all clays, if
such a substance really exists. Its absolute existence is by no means
proved, for, as will have been noticed, its composition is largely based
on assumption even in the most thorough investigations, particularly of
the admittedly less pure clays.
In the purer clays the problem is much simpler and in their case an
answer of at least approximate accuracy can be given to the question
'What is clay?'
Even with these purer clays it is not sufficient to study an analysis
showing the total amount of the silica, alumina and other oxides
present; it is still necessary to effect some kind of separation into
the various minerals of which they are composed. When, however, the
accessory minerals do not exceed 5 per cent. of the total ingredients
their influence is less important and the nature and characteristics of
the 'clay substance' itself can be more accurately studied. By careful
treatment of well selected china clays, for example, it is possible to
obtain a material corresponding to the formula Al2O3·2SiO2·2H2O
within a total error of 1 per cent., the small amount of impurity
being, as far as can be ascertained, composed of mica. So pure a
specimen of clay is found on microscopical examination to consist of
minute irregular grains of no definite form, together with a few
crystals of the same composition and identifiable as the mineral
'kaolinite' (p. 107). This 'amorphous' material, which appears to be the
chief constituent of all china clays and kaolins, has been termed
_clayite_ by Mellor (22).
Johnson and Blake, Aron and other observers have stated that the
majority of the particles in china clays and kaolins are crystalline in
form. Owing to their extreme smallness it is exceedingly difficult to
prove that they are not so, though for all ordinary purposes they may be
regarded as amorphous, the proportion of obviously crystalline matter
present in British china clay of the highest qualities being so small as
to be negligible.
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