M.P. Chappuis, in some very precise experiments conducted with much
method, has proved that at ordinary temperatures the indications of
such a thermometer are so close to the degrees of the theoretical
scale that it is almost impossible to ascertain the value of the
divergences, or even the direction that they take. The divergence
becomes, however, manifest when we work with extreme temperatures. It
results from the useful researches of M. Daniel Berthelot that we must
subtract +0.18° from the indications of the hydrogen thermometer
towards the temperature -240° C, and add +0.05° to 1000° to equate
them with the thermodynamic scale. Of course, the difference would
also become still more noticeable on getting nearer to the absolute
zero; for as hydrogen gets more and more cooled, it gradually exhibits
in a lesser degree the characteristics of a perfect gas.
To study the lower regions which border on that kind of pole of cold
towards which are straining the efforts of the many physicists who
have of late years succeeded in getting a few degrees further forward,
we may turn to a gas still more difficult to liquefy than hydrogen.
Thus, thermometers have been made of helium; and from the temperature
of -260° C. downward the divergence of such a thermometer from one of
hydrogen is very marked.
The measurement of very high temperatures is not open to the same
theoretical objections as that of very low temperatures; but, from a
practical point of view, it is as difficult to effect with an ordinary
gas thermometer. It becomes impossible to guarantee the reservoir
remaining sufficiently impermeable, and all security disappears,
notwithstanding the use of recipients very superior to those of former
times, such as those lately devised by the physicists of the
_Reichansalt_. This difficulty is obviated by using other methods,
such as the employment of thermo-electric couples, such as the very
convenient couple of M. le Chatelier; but the graduation of these
instruments can only be effected at the cost of a rather bold
extrapolation.
M.D. Berthelot has pointed out and experimented with a very
interesting process, founded on the measurement by the phenomena of
interference of the refractive index of a column of air subjected to
the temperature it is desired to measure. It appears admissible that
even at the highest temperatures the variation of the power of
refraction is strictly proportional to that of the density, for this
proportion is exactly verified so long as it is possible to check it
precisely. We can thus, by a method which offers the great advantage
of being independent of the power and dimension of the envelopes
employed--since the length of the column of air considered alone
enters into the calculation--obtain results equivalent to those given
by the ordinary air thermometer.
Public-domain text, read in full here on John Shaqi.
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