Consider an isothermal transformation. Instead of leaving the heat
abandoned by the body subjected to the transformation--water
condensing in a state of saturated vapour, for instance--to pass
directly into an ice calorimeter, we can transmit this heat to the
calorimeter by the intermediary of a reversible Carnot engine. The
engine having absorbed this quantity of heat, will only give back to
the ice a lesser quantity of heat; and the weight of the melted ice,
inferior to that which might have been directly given back, will serve
as a measure of the isothermal transformation thus effected. It can be
easily shown that this measure is independent of the apparatus used.
It consequently becomes a numerical element characteristic of the body
considered, and is called its entropy. Entropy, thus defined, is a
variable which, like pressure or volume, might serve concurrently with
another variable, such as pressure or volume, to define the state of a
body.
It must be perfectly understood that this variable can change in an
independent manner, and that it is, for instance, distinct from the
change of temperature. It is also distinct from the change which
consists in losses or gains of heat. In chemical reactions, for
example, the entropy increases without the substances borrowing any
heat. When a perfect gas dilates in a vacuum its entropy increases,
and yet the temperature does not change, and the gas has neither been
able to give nor receive heat. We thus come to conceive that a
physical phenomenon cannot be considered known to us if the variation
of entropy is not given, as are the variations of temperature and of
pressure or the exchanges of heat. The change of entropy is, properly
speaking, the most characteristic fact of a thermal change.
It is important, however, to remark that if we can thus easily define
and measure the difference of entropy between two states of the same
body, the value found depends on the state arbitrarily chosen as the
zero point of entropy; but this is not a very serious difficulty, and
is analogous to that which occurs in the evaluation of other physical
magnitudes--temperature, potential, etc.
A graver difficulty proceeds from its not being possible to define a
difference, or an equality, of entropy between two bodies chemically
different. We are unable, in fact, to pass by any means, reversible or
not, from one to the other, so long as the transmutation of matter is
regarded as impossible; but it is well understood that it is
nevertheless possible to compare the variations of entropy to which
these two bodies are both of them individually subject.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account