But there may be exceptional cases where the complexity of the system
becomes insufficient for the application of the principle of Carnot;--
as in the case of the curious movements of small particles suspended
in a liquid which are known by the name of Brownian movements and can
be observed under the microscope. The agitation here really seems, as
M. Gouy has remarked, to be produced and continued indefinitely,
regardless of any difference in temperature; and we seem to witness
the incessant motion, in an isothermal medium, of the particles which
constitute matter. Perhaps, however, we find ourselves already in
conditions where the too great simplicity of the distribution of the
molecules deprives the principle of its value.
M. Lippmann has in the same way shown that, on the kinetic hypothesis,
it is possible to construct such mechanisms that we can so take
cognizance of molecular movements that _vis viva_ can be taken from
them. The mechanisms of M. Lippmann are not, like the celebrated
apparatus at one time devised by Maxwell, purely hypothetical. They do
not suppose a partition with a hole impossible to be bored through
matter where the molecular spaces would be larger than the hole
itself. They have finite dimensions. Thus M. Lippmann considers a vase
full of oxygen at a constant temperature. In the interior of this vase
is placed a small copper ring, and the whole is set in a magnetic
field. The oxygen molecules are, as we know, magnetic, and when
passing through the interior of the ring they produce in this ring an
induced current. During this time, it is true, other molecules emerge
from the space enclosed by the circuit; but the two effects do not
counterbalance each other, and the resulting current is maintained.
There is elevation of temperature in the circuit in accordance with
Joule's law; and this phenomenon, under such conditions, is
incompatible with the principle of Carnot.
It is possible--and that, I think, is M. Lippmann's idea--to draw from
his very ingenious criticism an objection to the kinetic theory, if we
admit the absolute value of the principle; but we may also suppose
that here again we are in presence of a system where the prescribed
conditions diminish the complexity and render it, consequently, less
probable that the evolution is always effected in the same direction.
In whatever way you look at it, the principle of Carnot furnishes, in
the immense majority of cases, a very sure guide in which physicists
continue to have the most entire confidence.
§ 4. THERMODYNAMICS
To apply the two fundamental principles of thermodynamics, various
methods may be employed, equivalent in the main, but presenting as the
cases vary a greater or less convenience.
Public-domain text, read in full here on John Shaqi.
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