In the first place, the theory of Arrhenius explains electrolysis very
simply. The ions which, so to speak, wander about haphazard, and are
uniformly distributed throughout the liquid, steer a regular course as
soon as we dip in the trough containing the electrolyte the two
electrodes connected with the poles of the dynamo or generator of
electricity. Then the charged positive ions travel in the direction of
the electromotive force and the negative ions in the opposite
direction. On reaching the electrodes they yield up to them the
charges they carry, and thus pass from the state of ion into that of
ordinary atom. Moreover, for the solution to remain in equilibrium,
the vanished ions must be immediately replaced by others, and thus the
state of ionisation of the electrolyte remains constant and its
conductivity persists.
All the peculiarities of electrolysis are capable of interpretation:
the phenomena of the transport of ions, the fine experiments of M.
Bouty, those of Professor Kohlrausch and of Professor Ostwald on
various points in electrolytic conduction, all support the theory. The
verifications of it can even be quantitative, and we can foresee
numerical relations between conductivity and other phenomena. The
measurement of the conductivity permits the number of molecules
dissociated in a given solution to be calculated, and the number is
thus found to be precisely the same as that arrived at if it is wished
to remove the disagreement between reality and the anticipations which
result from the theory of Professor Van t' Hoff. The laws of
cryoscopy, of tonometry, and of osmosis thus again become strict, and
no exception to them remains.
If the dissociation of salts is a reality and is complete in a dilute
solution, any of the properties of a saline solution whatever should
be represented numerically as the sum of three values, of which one
concerns the positive ion, a second the negative ion, and the third
the solvent. The properties of the solutions would then be what are
called additive properties. Numerous verifications may be attempted by
very different roads. They generally succeed very well; and whether we
measure the electric conductivity, the density, the specific heats,
the index of refraction, the power of rotatory polarization, the
colour, or the absorption spectrum, the additive property will
everywhere be found in the solution.
The hypothesis, so contested at the outset by the chemists, is,
moreover, assuring its triumph by important conquests in the domain of
chemistry itself. It permits us to give a vivid explanation of
chemical reaction, and for the old motto of the chemists, "Corpora non
agunt, nisi soluta," it substitutes a modern one, "It is especially
the ions which react." Thus, for example, all salts of iron, which
contain iron in the state of ions, give similar reactions; but salts
such as ferrocyanide of potassium, in which iron does not play the
part of an ion, never give the characteristic reactions of iron.
Public-domain text, read in full here on John Shaqi.
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