Professor Ostwald and his pupils have drawn from the hypothesis of
Arrhenius manifold consequences which have been the cause of
considerable progress in physical chemistry. Professor Ostwald has
shown, in particular, how this hypothesis permits the quantitative
calculation of the conditions of equilibrium of electrolytes and
solutions, and especially of the phenomena of neutralization. If a
dissolved salt is partly dissociated into ions, this solution must be
limited by an equilibrium between the non-dissociated molecule and the
two ions resulting from the dissociation; and, assimilating the
phenomenon to the case of gases, we may take for its study the laws of
Gibbs and of Guldberg and Waage. The results are generally very
satisfactory, and new researches daily furnish new checks.
Professor Nernst, who before gave, as has been said, a remarkable
interpretation of the diffusion of electrolytes, has, in the direction
pointed out by M. Arrhenius, developed a theory of the entire
phenomena of electrolysis, which, in particular, furnishes a striking
explanation of the mechanism of the production of electromotive force
in galvanic batteries.
Extending the analogy, already so happily invoked, between the
phenomena met with in solutions and those produced in gases, Professor
Nernst supposes that metals tend, as it were, to vaporize when in
presence of a liquid. A piece of zinc introduced, for example, into
pure water gives birth to a few metallic ions. These ions become
positively charged, while the metal naturally takes an equal charge,
but of contrary sign. Thus the solution and the metal are both
electrified; but this sort of vaporization is hindered by
electrostatic attraction, and as the charges borne by the ions are
considerable, an equilibrium will be established, although the number
of ions which enter the solution will be very small.
Public-domain text, read in full here on John Shaqi.
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