If the liquid, instead of being a solvent like pure water, contains an
electrolyte, it already contains metallic ions, the osmotic pressure
of which will be opposite to that of the solution. Three cases may
then present themselves--either there will be equilibrium, or the
electrostatic attraction will oppose itself to the pressure of
solution and the metal will be negatively charged, or, finally, the
attraction will act in the same direction as the pressure, and the
metal will become positively and the solution negatively charged.
Developing this idea, Professor Nernst calculates, by means of the
action of the osmotic pressures, the variations of energy brought into
play and the value of the differences of potential by the contact of
the electrodes and electrolytes. He deduces this from the
electromotive force of a single battery cell which becomes thus
connected with the values of the osmotic pressures, or, if you will,
thanks to the relation discovered by Van t' Hoff, with the
concentrations. Some particularly interesting electrical phenomena
thus become connected with an already very important group, and a new
bridge is built which unites two regions long considered foreign to
each other.
The recent discoveries on the phenomena produced in gases when
rendered conductors of electricity almost force upon us, as we shall
see, the idea that there exist in these gases electrified centres
moving through the field, and this idea gives still greater
probability to the analogous theory explaining the mechanism of the
conductivity of liquids. It will also be useful, in order to avoid
confusion, to restate with precision this notion of electrolytic ions,
and to ascertain their magnitude, charge, and velocity.
The two classic laws of Faraday will supply us with important
information. The first indicates that the quantity of electricity
passing through the liquid is proportional to the quantity of matter
deposited on the electrodes. This leads us at once to the
consideration that, in any given solution, all the ions possess
individual charges equal in absolute value.
The second law may be stated in these terms: an atom-gramme of metal
carries with it into electrolysis a quantity of electricity
proportionate to its valency.[19]
[Footnote 19: The valency or atomicity of an element may be defined as
the power it possesses of entering into compounds in a certain fixed
proportion. As hydrogen is generally taken as the standard, in
practice the valency of an atom is the number of hydrogen atoms it
will combine with or replace. Thus chlorine and the rest of the
halogens, the atoms of which combine with one atom of hydrogen, are
called univalent, oxygen a bivalent element, and so on.--ED.]
Public-domain text, read in full here on John Shaqi.
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