The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
Components.--Although the conception of phases is one which is readily
understood, somewhat greater difficulty is experienced when we come to
consider what is meant by the term _component_; for the components of a
system are not synonymous with the chemical elements or compounds present,
_i.e._ with the _constituents_ of the system, although both elements and
compounds may be components. By the latter term there are meant only those
constituents the concentration of which can undergo _independent_ variation
in the different phases, and it is only with these that we are concerned
here.[15]
To understand the meaning of this term we shall consider briefly some cases
with which the reader will be familiar, and at the outset it must be
emphasized that the Phase Rule is concerned merely with those constituents
which take part in the state of real equilibrium (p. 5); for it is only to
the final state, not to the processes by which that state is reached, that
the Phase Rule applies.
Consider now the case of the system water--vapour or ice--water--vapour.
The number of constituents taking part in the equilibrium here is only one,
viz. the chemical substance, water. Hydrogen and oxygen, the constituents
of water, are not to be regarded as components, because, in the first
place, they are {11} not present in the system in a state of real
equilibrium (p. 6); in the second place, they are combined in definite
proportions to form water, and their amounts, therefore, cannot be varied
independently. A variation in the amount of hydrogen necessitates a
definite variation in the amount of oxygen.
In the case, already referred to, in which hydrogen and oxygen are present
along with water at the ordinary temperature, we are not dealing with a
condition of true equilibrium. If, however, the temperature is raised to a
certain point, a state of true equilibrium between hydrogen, oxygen, and
water-vapour will be possible. In this case hydrogen and oxygen will be
components, because now they do take part in the equilibrium; also, they
need no longer be present in definite proportions, but excess of one or the
other may be added. Of course, if the restriction be arbitrarily made that
the free hydrogen and oxygen shall be present always and only in the
proportions in which they are combined to form water, there will be, as
before, only one component, water. From this, then, we see that a change in
the conditions of the experiment (in the present case a rise of
temperature) may necessitate a change in the number of the components.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account