The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
If no compound is formed between the two components, {209} the general form
of the equilibrium curve will be that of curve I. or II., Fig. 63. Type I.
is the simplest form of curve found, and consists, as the diagram shows, of
only two branches, AC and BC, meeting at the point C, _which lies below the
melting point of either component_. The solid phase which is in equilibrium
with the solutions AC is pure A; that in equilibrium with BC, pure B. C is
the eutectic point. Although at the eutectic point the solution solidifies
entirely without change of temperature, the solid which is deposited is not
a homogeneous solid phase, but a mixture, or conglomerate of the two
components. _The eutectic point, therefore, represents the melting or
freezing point, not of a compound, but of a mixture_ (p. 119).
Curve II., Fig. 63, is obtained when two liquid phases are formed. C is an
eutectic point, D and F are transition points at which there can co-exist
the four phases--solid, two liquid phases, vapour. DEF represents the
change in the composition of the two liquid phases with rise of
temperature; the curve might also have the reversed form with the critical
solution point below the transition points D and F.
[Illustration: FIG. 64.]
In the second class of systems (Fig. 64), that in which combination between
the components occurs, there are again two types according as the compound
formed has a definite melting point (_i.e._ can exist in equilibrium with a
solution of the same composition), or undergoes only partial fusion; that
is, exhibits a transition point.
If a compound possessing a definite melting point is formed, the
equilibrium curve will have the general form shown by curve I., Fig. 64. A,
B, and D are the melting points of pure A, pure B, and of the compound
A_{x}B_{y} respectively. AC {210} is the freezing point curve of A in
presence of B; BE that of B in presence of A; and DC and DE the freezing
point curves of the compound in presence of a solution containing excess of
one of the components. C and E are eutectic points at which mixtures of A
and A_{x}B_{y}, or B and A_{x}B_{y} can co-exist in contact with solution.
The curve CDE may be large or small, and the melting point of the compound,
D, may lie above or below that of each of the components, or may have an
intermediate position. If more than one compound can be formed, a series of
curves similar to CDE will be obtained (_cf._ p. 152).
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