The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
The interest and importance of investigations into the conditions of
equilibrium between two substances, lie in the determination not only of
the conditions for the stable existence of the participating substances,
but also of whether or not chemical action takes place between these two
components; and if combination occurs, in the determination of the nature
of the compounds formed and the range of their existence. In all such
investigations, the Phase Rule becomes of conspicuous value on account of
the fact that its principles afford, as it were, a touchstone by which the
character of the system can be determined, and that from the form of the
equilibrium curves obtained, conclusions can be drawn as to the nature of
the interaction between the two substances. In order to exemplify the
application of the principles of the Phase Rule more fully than has already
been done, illustrations will be drawn from investigations on the
interaction of organic compounds; on the equilibria between optically
active compounds; and on alloys. {208}
Summary of the Different Systems of Two Components.--Before passing to the
consideration of the application of the Phase Rule to the investigation of
particular problems, it will be well to collect together the different
types of equilibrium curves with which we are already acquainted; to
compare them with one another, in order that we may then employ these
characteristic curves for the interpretation of the curves obtained as the
result of experiment.
In investigating the equilibria between two components, three chief classes
of curves will be obtained according as--
I. No combination takes place between the two components.
II. The components can form definite compounds.
III. The components separate out in the form of mixed crystals.
The different types of curves which are obtained in these three cases are
represented in Figs. 63, 64, 65. These different diagrams represent the
whole series of equilibria, from the melting point of the one component (A)
to that of the other component (B). The curves represent, in all cases, the
composition of the solution, or phase of variable composition; the
temperature being measured along one axis, and the composition along the
other.
We shall now recapitulate very briefly the characteristics of the different
curves.
[Illustration: FIG. 63.]
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