The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
The different modifications of iron also possess different properties.
Thus, [alpha]-ferrite is magnetic, but does not possess the power of
dissolving carbon; [beta]-ferrite is non-magnetic, and likewise does not
dissolve carbon; [gamma]-ferrite is also non-magnetic, but possesses the
power of dissolving carbon, and of thus giving rise to solid solutions of
carbon in iron.
Various alloys of iron and carbon, also, have to be distinguished. First of
all, there is _hard steel_, which contains varying amounts of carbon up to
2 per cent. Microscopic examination shows that these mixtures are all
homogeneous; and they are therefore to be regarded as solid solutions of
carbon in iron ([gamma]-ferrite). To these solutions the name _martensite_
has been given. _Pearlite_ contains about 0.8 per cent. of carbon, and, on
microscopic examination, is found to be a heterogeneous mixture. If heated
above 670°, pearlite becomes homogeneous, and forms martensite. Lastly,
there is a definite compound of iron and carbon, iron carbide or
_cementite_, having the formula Fe_{3}C.
A short description may now be given of the application of the Phase Rule
to the two-component system iron--carbon; and of the diagram showing how
the different systems are related, and with the help of which the behaviour
of the different mixtures under given conditions can be predicted.
Although, with regard to the main features of this diagram, the different
areas to be mapped and the position of the frontier lines, there is general
agreement; a final decision has not yet been reached with regard to the
interpretation to be put on all the curves.
[Illustration: FIG. 75.]
The chief relationships met with in the case of the {225} iron-carbon
alloys are represented graphically in Fig. 75.[309] The curve AC is the
freezing-point curve for iron,[310] BC the unknown freezing-point curve for
graphite. C is an eutectic point. Suppose, now, that we start with a
mixture of iron and carbon, represented by the point _x_. On lowering the
temperature, a point, _y_, will be reached at which solid begins to
separate out. This solid phase, however, is not pure iron, but a solid
solution of carbon in iron, having the composition represented by _y'_ (cf.
p. 185). As the temperature continues to fall, the {226} composition of the
liquid phase changes in the direction of _y_C, while the composition of the
solid which separates out changes in the direction _y'_D; and, finally,
when the composition of the molten mass is that of the point C (4.3 per
cent. of carbon), the whole mass solidifies to a heterogeneous mixture of
two solid solutions, one of which is represented by D (containing 2 per
cent. of carbon), while the other will consist practically of pure
graphite, and is not shown in the figure. The temperature of the eutectic
point is 1130°.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account