The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
Even below the solidification point, however, changes can take place. As
has been said, the solid phase which finally separates out from the molten
mass is a solid solution represented by the point D; and the curve DE
represents the change in the composition of this solid solution with the
temperature. As indicated in the figure, DE forms a part of a curve
representing the mutual solubility of graphite in iron and iron in
graphite; the latter solutions, however, not being shown, as they would lie
far outside the diagram. As the temperature falls below 1130°, more and
more graphite separates out, until at E, when the temperature is 1000°, the
solid solution contains only 1.8 per cent. of carbon. At this temperature
cementite also begins to be formed, so that as the temperature continues to
fall, separation of cementite (represented by the line E'F') occurs, and
the composition of the solid solution undergoes alteration, as represented
by the curve EF. Below the temperature of the point F (670°) the martensite
becomes heterogeneous, and forms pearlite.
From the above description, therefore, it follows that if we start with a
molten mixture of iron and carbon, the composition of which is represented
by any point between D and C (from 2 to 4.3 per cent. of carbon), we shall
obtain, on cooling the mass, first of all solid solutions, the composition
of which will be represented by points on the line AD; that then, after the
mass has completely solidified at 1130°, further cooling will lead to a
separation of graphite and a change in the composition of the martensite
(from 2 to 1.8 per cent. of carbon). On cooling below 1000°, however, the
martensite and graphite will give rise to cementite and solid solutions
{227} containing less carbon than before, until, at temperatures below
670°, we are left with a mixture of pearlite and cementite.
We have already said that iron consists in three allotropic modifications,
the regions of stability of which are separated by definite transition
points. The transition point for [alpha]- and [beta]-ferrite (780°) is
represented in Fig. 75 by the point H; and the transition point for [beta]-
and [gamma]-ferrite (870°) by the point I. Since neither the [alpha]- nor
the [beta]-ferrite dissolves carbon, the transition point will be
unaffected by addition of carbon, and we therefore obtain the horizontal
transition curve HG. In the case of the [beta]- and [gamma]-ferrite,
however, the latter dissolves carbon, and the transition point is
consequently affected by the amount of carbon present. This is shown by the
line IG.
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