The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
If a martensite containing less carbon than that represented by the point G
is cooled down from a temperature of, say, 900°, then when the temperature
has fallen to that, represented by a point on the curve IG, [beta]-ferrite
will separate out, and, as the temperature falls, the composition of the
solid solution will alter as represented by IG. On passing below the
temperature of HG, the [beta]-ferrite will be converted into
[alpha]-ferrite, and, as the temperature falls, the latter will separate
out more and more, while the composition of the solid solution alters in
the direction GF. On passing to still lower temperatures, the solid
solution at F (0.8 per cent. of carbon) breaks up into pearlite. If the
percentage of carbon in the original solid solution was between that
represented by the points G and F, then, on cooling down, no
[beta]-ferrite, but only [alpha]-ferrite would separate out.
We see, therefore, that when martensite is allowed to cool _slowly_, it
yields a heterogeneous mixture either of ferrite and pearlite (when the
original mixture contained up to 0.8 per cent. of carbon), or pearlite and
cementite (when the original mixture contained between 0.8 and 2 per cent.
of carbon). These heterogeneous mixtures constitute soft steels, or, when
the carbon content is low, wrought iron.
The case, however, is different if the solid solution of carbon in iron is
_rapidly_ cooled (quenched) from a temperature above the curve IGFE to a
temperature below this {228} curve. In this case, the rapid cooling does
not allow time for the various changes which have been described to take
place; so that the homogeneous solid solution, on being rapidly cooled,
remains homogeneous. In this way hard steel is obtained. By varying the
rapidity of cooling, as is done in the tempering of steel, varying degrees
of hardness can be obtained.
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