The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
From the example which has just been discussed, it might {13} appear as if
the choice of the components was rather arbitrary. On examining the point,
however, it will be seen that the arbitrariness affects only the _nature_,
not the _number_, of the components; a choice could be made with respect to
which, not to how many, constituents were to be regarded as components. As
we shall see presently, however, it is only the number, not the nature of
the components that is of importance.
After the discussion of the conditions which the substances chosen as
components must satisfy, another method may be given by which the number of
components present in a system can be determined. Suppose a system
consisting of several phases in equilibrium, and the composition of each
phase determined by analysis. If each phase present, regarded as a whole,
has the same composition, the system contains only one component, or is of
the first order. If two phases must be mixed in suitable quantities in
order that the composition of a third phase may be obtained, the system is
one of two components or of the second order; and if three phases are
necessary to give the composition of a fourth coexisting phase, the system
is one of three components, or of the third order.[16]
Although the examples to be considered in the sequel will afford sufficient
illustration of the application of the rules given above, one case may
perhaps be discussed to show the application of the method just given for
determining the number of components.
Consider the system consisting of Glauber's salt in equilibrium with
solution and vapour. If these three phases are analyzed, the composition of
the solid will be expressed by Na_{2}SO_{4}, 10H_{2}O; that of the solution
by Na_{2}SO_{4} + _x_H_{2}O, while the vapour phase will be H_{2}O. The
system evidently cannot be a one-component system, for the phases have not
all the same composition. By varying the amounts of two phases, however
(_e.g._ Na_{2}SO_{4}, 10H_{2}O and H_{2}O), the composition of the third
phase--the solution--can be obtained. The system is, therefore, one of _two
components_.
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