The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
Another method of representation, due to Roozeboom, consists in employing
an equilateral triangle, the length of whose _side_ is made equal to unity,
or one hundred; the sum of the fractional or percentage amounts of the
three components being represented therefore by a side of the triangle. In
this case the composition of a ternary mixture is obtained by determining,
not the _perpendicular_ distance of a point P from the three sides of the
triangle, but the distance in a direction _parallel_ to the sides of the
triangle (Fig. 81). Conversely, in order to represent a mixture consisting
of _a_, _b_, and _c_ parts of the components A, B, and C respectively, one
side of the triangle, say AB, is first of all divided into ten or one {238}
hundred parts; a portion, B_x_ = _a_, is then measured off, and represents
the amount of A present. Similarly, a portion, A_x'_ = _b_, is measured off
and represents the fractional amount of B, while the remainder, _xx'_ =
_c_, represents the amount of C. From _x_ and _x'_ lines are drawn parallel
to the sides of the triangle, and the point of intersection, P, represents
the composition of the ternary mixture of given composition; for, as is
evident from the figure, the distance of the point P from the three sides
of the triangle, when measured in directions _parallel_ to the sides, is
equal to _a_, _b_, and _c_ respectively. From the division marks on the
side AB, it is seen that the point P in this figure also represents a
mixture of 0.5 parts of A, 0.2 parts of B, and 0.3 parts of C. This gives
exactly the same result as the previous method. The employment of a
right-angled isosceles triangle has also been suggested,[319] but is not in
general use.
[Illustration: FIG. 81.]
In employing the triangular diagram, it will be of use to note a property
of the equilateral triangle. A line drawn from one corner of the triangle
to the opposite side, represents the composition of all mixtures in which
the _relative_ amounts of two of the components remain unchanged. Thus, as
Fig. 82 shows, if the component C is added to a mixture x, in which A and B
are present in the proportions of _a_ : _b_, a mixture _x'_, which is
thereby obtained, also contains A and B in the ratio _a_ : b. For the two
triangles AC_x_ and BC_x_ are similar to the two triangles HC_x'_ and
KC_x'_; and, {239} therefore, A_x_ : B_x_ = H_x'_ : K_x'_. But A_x_ = D_x_
and B_x_ = E_x_; further H_x'_ = F_x'_ and K_x'_ = G_x'_. Therefore, D_x_ :
E_x_ = F_x'_ : G_x'_ = _b_ : a. At all points on the line C_x_, therefore,
the ratio of A to B is the same.
[Illustration: FIG. 82.]
[Illustration: FIG. 83.]
If it is desired to represent at the same time the change of another
independent variable, _e.g._ temperature, this can be done by measuring the
latter along axes drawn perpendicular to the corners of the triangle. In
this way a right prism (Fig. 83) is obtained, and each section of this cut
parallel to the base represents therefore an _isothermal surface_.
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