The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
In the method proposed by Gibbs an equilateral triangle of unit height is
used (Fig 80).[318] The quantities of the different components are
expressed as fractional parts of the whole, and the sum of their
concentrations is therefore equal to unity, and can be represented by the
height of the triangle. The corners {237} of the triangle represent the
pure substances A, B, and C respectively. A point on one of the sides of
the triangle will give the composition of a mixture in which only two
components are present, while a point within the triangle will represent
the composition of a ternary mixture. Since every point within the triangle
has the property that the sum of the perpendiculars from that point on the
sides of the triangle is equal to unity (the height of the triangle), it is
evident that the composition of a ternary mixture can be represented by
fixing a point within the triangle such that the lengths of the
_perpendiculars_ from the point to the sides of the triangle are equal
respectively to the fractional amounts of the three components present; the
fractional amount of A, B, or C being represented by the perpendicular
distance from the side of the triangle _opposite_ the corners A, B, and C
respectively.
The location of this point is simplified by dividing the normals from each
of the corners on the opposite side into ten or one hundred parts, and
drawing through these divisions lines at right angles to the normal and
parallel to the side of the triangle. A network of rhombohedra is thus
obtained, and the position of any point can be read off in practically the
same manner as in the case of rectangular co-ordinates. Thus the point P in
Fig. 80 represents a ternary mixture of the composition A = 0.5, B = 0.3, C
= 0.2; the perpendiculars P_a_, P_b_, and P_c_ being equal respectively to
0.5, 0.2, and 0.3 of the height of the triangle.
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