The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
------+---------------------+
|Initial composition |
|of the solutions: |
|grams of salt to 1000|
Point.|grams of water. |
+------+--------------+
| NaCl | NH_{4}HCO_{3}|
------+------+--------------+
P_{1} | 397 | 496 |
-- | 351 | 446 |
-- | 316 | 412 |
-- | 294 | 389 |
-- | 234 | 327 |
------+------+--------------+
[Transcriber's note: table continued below...]
+----------------------------------+------+----------
| | |
|Composition of solutions obtained:| |
|in gram-equivalents per 1000 grams|U_{Na}|U_{NH_{4}}
|of water. | |
+----------+------+------+---------+ |
| HCO_{3} | Cl | Na | NH_{4} | |
+----------+------+------+---------+------+----------
| 0.92 | 6.79 | 1.44 | 6.28 | 78.8 | 85.1
| 0.99 | 6.00 | 1.34 | 5.65 | 77.7 | 82.5
| 1.07 | 5.41 | 1.27 | 5.21 | 76.4 | 79.5
| 1.12 | 5.03 | 1.23 | 4.92 | 75.5 | 75.1
| 1.30 | 4.00 | 1.16 | 4.14 | 71.0 | 68.6
+----------+------+------+---------+------+----------
As is evident from this table, diminution in the relative amount of sodium
chloride exercises only a slight influence {325} on the utilization of this
salt, but is accompanied by a rapid diminution of the effective
transformation of the ammonium bicarbonate. So far as the efficient
conversion of the sodium is concerned, we see that it reaches its maximum
at the point P_{1}, and that it decreases both with increase and with
decrease of the relative amount of sodium chloride employed; and faster,
indeed, in the former than in the latter case. On the other hand, the
effective transformation of the ammonium bicarbonate reaches its maximum at
the point P_{2}, and diminishes with increase in the relative amount of
ammonium bicarbonate employed. Since sodium chloride is, in comparison with
ammonia--even when this is regenerated--a cheap material, it is evidently
more advantageous to work with solutions which are relatively rich in
sodium chloride (solutions represented by the curve P_{1}P_{2}). This fact
has also been established empirically.
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