The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
[103] These changes can be predicted quantitatively by means of the
thermodynamic equation, _dp_/_dt_ = Q/(T(_v_{2}_ - _v_{1}_)), provided the
specific volumes of the phases are known, and the heat effect which
accompanies the transformation of one phase into the other.
[104] _Studies on Chemical Dynamics_, translated by Ewan, p. 218.
[105] Le Chatelier, _Compt. rend._, 1884, 99. 786.
[106] See _Principles of Inorganic Chemistry_, translated by Findlay, 2nd
edit., p. 133. (Macmillan, 1904.)
[107] Roozeboom, _Zeitschr. physikal. Chem._, 1888, 2. 474.
[108] Roozeboom, _Das Heterogene Gleichgewicht_, I. p. 189.
[109] Roozeboom, _Das Heterogene Gleichgewicht_, I. p. 125. See also
Zawidski, _Zeitschr. physikal. Chem._, 1904, 47. 727; van Eyk, _ibid._,
1905, 51. 720.
[110] Roberts-Austen, _Proc. Roy. Soc._, 63. 454; Spring, _Zeitschr.
physikal. Chem._, 1894, 15. 65. See also p. 35.
[111] Ramsay and Young, _Phil. Trans._, 1884, 175. 461; Allen, _Trans.
Chem. Soc._, 1900, 77. 413.
[112] Ramsay and Young, _Phil. Trans._ 1886, 177. 87.
[113] This is exemplified in the well-known experiment with the cryophorus.
[114] Tammann has, however, found that the fusion curve (solid in contact
with liquid) of phosphonium chloride can be followed up to temperatures
above the critical point (_Arch. néer._, 1901 [2], 6. 244).
[115] _Phil. Mag._, 1886, 21. 33. See also S. A. Moss, _Physical Review_,
1903, 16. 356.
[116] This is found also in the case of bismuth. See Tammann, _Zeitschr.
anorgan. Chem._, 1904, 40. 54.
[117] See p. 57, footnote.
[118] _Pogg. Annalen_, 1850, 81. 562.
[119] Barus, _Amer. Jour. Sci._, 1892, 42. 125; Mack, _Compt. rend._, 1898,
127. 361; Hulett, _Zeitschr. physikal. Chem._, 1899, 38. 629.
[120] _Annalen der Physik_, 1899 [3], 68. 553, 629; 1900 [4], 1. 275; 2.
1; 3. 161. See also Tammann, _Kristallisieren und Schmelzen_ (Leipzig,
1903).
[121] Ostwald, _Lehrbuch_, II. 2. 373; Poynting, _Phil. Mag._, 1881 [5],
12. 2; Planck, _Wied. Annalen_, 1882, 15. 446.
[122] Bakhuis Roozeboom, _Das Heterogene Gleichgewicht_, I. p. 91.
[123] Lussana, _Il nuovo Cimento_, 1895 [4], 1. 105.
[124] Tammann, _Zeitschr. physikal. Chem._, 1903, 46. 818.
[125] Foote, _Zeitschr. physikal. Chem._, 1900, 33. 740.
[126] Ostwald, _Zeitschr. physikal. Chem._, 1897, 22. 289.
[127] Van't Hoff, _Arch, néer._, 1901, 6. 471.
[128] See, for example, the determinations of the solubility of rhombic and
monoclinic sulphur, by J. Meyer, _Zeitschr. anorg. Chem._, 1902, 33. 140.
[129] _Zeitschr. physikal. Chem._, 1899, 32. 506.
[130] Kastle and Reed, _Amer. Chem. Jour._, 1902, 27. 209.
[131] _Zeitschr. physikal. Chem._, 1900, 35. 581.
[132] _Compt. rend._, 1882, 95. 1278; 1884, 97. 1298, 1366, 1433.
[133] _Zeitschr. physikal. Chem._, 1893, 12. 545.
[134] _Sitzungsber. Wiener Akad._, 1894, 103. IIa. 226.
[135] _Zeitschr. physikal. Chem._, 23-29. See also Küster, _ibid._, 25-28.
[136] _Zeitschr. physikal. Chem._, 1897, 24. 152.
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