The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
[269] Küster, _Zeitschr. physikal. Chem._, 1895, 17. 360.
[270] Küster, _ibid._, 1891, 8. 589.
[271] It should be remarked that the behaviour described here will hold
strictly only when the solid mixed crystals undergo change sufficiently
rapidly to be always in equilibrium with the liquid. This, however, is not
always the case (see Reinders, _Zeitschr. physikal. Chem._, 1900, 32. 494;
van Wyk, _Zeitschr. anorg. Chem._, 1905, 48. 25), and complete
solidification will not in this case take place at the temperature
corresponding with the line _dc_ in Fig. 50, but only at a lower
temperature.
[272] Adriani, _Zeitschr. physikal. Chem._, 1900, 33. 469.
[273] Reinders, _Zeitschr. physikal. Chem._, 1900, 32. 494.
[274] Hissink, _Zeitschr. physikal. Chem._, 1900, 32. 542.
[275] Van Eyk, _Zeitschr. physikal. Chem._, 1899, 30. 430.
[276] Cady, _Journ. Physical. Chem._, 1899, 3. 127.
[277] See Roberts-Austen and Stansfield, _Rapports du congrès international
de physique_, 1900, I. 363.
[278] Heycock and Neville, _Proc. Roy. Soc._, 1903, 71. 409. For the
partial liquefaction of mixed crystals on cooling, see also A. C. de Kock
(_Zeitschr. physikal. Chem._, 1904, 48. 129).
[279] Armstrong, _Watt's Dictionary of Chemistry_ (Morley and Muir), III.,
p. 88. See also Lowry, _Jour. Chem. Soc._, 1899, 75. 211.
[280] See Bancroft, _Journ. Physical Chem._, 1898, 2. 143; Roozeboom,
_Zeitschr. physikal. Chem._, 1899, 28. 288.
[281] Hylotropic substances are such as can undergo transformation into
other substances of the same composition (Ostwald, _Lehrbuch_, II. 2. 298).
[282] Also called Equilibrium Point (Lowry).
[283] For a discussion of these systems, see Roozeboom, _Zeitschr.
physikal. Chem._, _loc. cit_.
[284] See Bancroft, _loc. cit._, p. 147; Wegscheider, _Sitzungsber. Wiener
Akad._, 1902, 110. 908.
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