The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
[285] Reference may be made here to the term "stability limit," introduced
by Knorr (_Annalen_, 1896, 293. 88) to indicate that temperature above
which liquefaction and isomeric change takes place. As employed by Knorr
and others, the term does not appear to have a very precise meaning, since
it is used to denote, not the temperature at which these changes can occur,
but the temperature at which the change is rapid (vide _Annalen_, 1896,
293. 91; 1899, 306. 334); and the introduction of an indefinite velocity of
change renders the temperature of the stability limit also somewhat
indefinite. The definiteness of the term is also not a little diminished by
the fact that the "limit" can be altered by means of catalytic agents.
Since, as we have seen, the stable modification can always undergo isomeric
change and liquefy at temperatures above the natural freezing point, but
not below that point; and, further, the less stable modification can
undergo isomeric transformation and liquefy at temperatures above the
eutectic point, but will not liquefy at temperatures below that; it seems
to the author that it would be more precise to identify these two
points--the natural freezing point and the eutectic point--which are not
altered by catalytic agents, with the "stability limits" of the stable and
unstable modification respectively. A perfectly definite meaning would
thereby be given to the term. In the case of those substances which do not
undergo appreciable isomeric change at the temperature of the melting
point, the stability limits would be the points G and H, Fig. 60.
[286] Cameron, _Journ. Physical Chem._, 1898, 2. 409.
[287] Carveth, _Journ. Phys. Chem._, 1898, 2. 159. See also Dutoit and
Fath, _Journ. chim. phys_., 1903, 1. 358; Findlay, _Trans. Chem. Soc._,
1904, 85. 403.
[288] Hollmann, _Zeitschr. physikal. Chem._, 1903, 43. 129.
[289] For other examples of the application of the Phase Rule to isomeric
substances, see _Journ. Physical Chem._, vols. 2. _et seq._; Findlay,
_Trans. Chem. Soc._, 1904, 85. 403.
[290] See Roozeboom, _Zeitschr. physikal. Chem._, 1899, 30. 410.
[291] See also Saposchnikoff, _Zeitschr. physikal. Chem._, 49. 688;
Kremann, _Monatshefte_, 1904, 25. 1215, 1271, 1311.
[292] J. C. Philip, _Journ. Chem. Soc._, 1903, 83. 821.
[293] _Cf._ also Paterno and Ampolla, _Gazzetta chim. ital._, 1897, 27.
481.
[294] Philip, _loc. cit._, p. 826.
[295] Philip, _loc. cit._, p. 829. Compare curves for iodine monochloride,
Fig. 42, p. 162.
[296] Kuriloff, _Zeitschr. physikal. Chem._, 1897, 23. 676.
[297] Ladenburg, _Ber._, 1895, 28. 163; 1991.
[298] Roozeboom, _Zeitschr. physikal. Chem._, 1899, 28. 494; Adriani,
_ibid._, 1900, 33. 453.
[299] Adriani, _Zeitschr. physikal. Chem._, 1900, 33. 453.
[300] A. Findlay and Miss E. Hickmans.
[301] Kipping and Pope, _Journ. Chem. Soc._, 1897, 71. 993.
[302] See Roozeboom, _Zeitschr. physikal. Chem._, 1899, 28. 512; Adriani,
_ibid._, 1900, 33. 473; 1901, 36. 168.
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