The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
When mercury and water are brought together, the two liquids remain side by
side without mixing. Strictly speaking, mercury undoubtedly dissolves to a
certain extent in the water, and water no doubt dissolves, although to a
less extent, in the mercury; the amount of substance passing into solution
is, however, so minute, that it may, for all practical purposes, be left
out of account, so long as the temperature does not rise much above the
ordinary.[166] On the other hand, if alcohol and water be brought together,
complete miscibility takes place, and one homogeneous solution is obtained.
Whether water be added in increasing quantities to pure alcohol, or pure
alcohol be added in increasing amount to water, at no point, at no degree
of concentration, is a system obtained containing more than one liquid
phase. At the ordinary temperature, water and alcohol can form only two
phases, liquid and vapour. If, however, water be added to ether, or if
ether be added to water, solution will not occur to an indefinite extent;
but a point will be reached when the water or the ether will no longer
dissolve more of the other component, and a further addition of water on
the one hand, or ether on the other, will cause the formation of two liquid
layers, one containing excess of water, the other excess of ether. We
shall, therefore, expect to find all grades of miscibility, from almost
perfect immiscibility to perfect miscibility, or miscibility in all
proportions. In cases of perfect immiscibility, the components do not
affect one another, and the system therefore remains unchanged. Such cases
do not call for treatment here. We have to concern ourselves here only with
the second and third cases, viz. with cases of complete and of partial
miscibility. There is no essential difference between the two classes, for,
as we shall see, {96} the one passes into the other with change of
temperature. The formal separation into two groups is based on the
miscibility relations at ordinary temperatures.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account