Much of the lime on the market in the Philippines has been made
without any attempt to select pure clean limestone or shells. This is
not suitable for putting into cane juice, and will result in a great
deal of trouble whenever used in modern evaporating plants. There is,
however, an abundant supply of limestone found in various parts of the
Philippines, which analyses show to be almost free from impurities, and
which will make a most excellent lime for clarifying purposes if burned
properly. At present there is no modern plant for burning this rock
on a large scale and consequently much of the work is done in a very
crude and unsatisfactory manner. Most of the lime for clarification,
in modern sugar factories, is imported, and constitutes a very heavy
expense. If a lime kiln were installed in conjunction with some of
our sugar factories, fresh and well-burned lime might be made as
needed. The carbon dioxide could be used in the juice clarification,
as is done in Java, and thus a good grade of plantation sugar could
easily be manufactured. Any excess of burned lime might very readily be
sold to other factories, which now use only high-priced imported lime.
The lime used should be of the unslaked type, and should be protected
from the air until a short time before using. The process of preparing
this consists of heating lime rock to a very high temperature, in
a kiln for that purpose, whereby the limestone is broken into two
component parts, expressed by the following chemical equation: CaCO3
(limestone) heated to high temperature-->CaO (calcium oxide) + CO2
(carbon dioxide). This calcium oxide, commonly known as "quick lime,"
is the substance desired in clarification. It should be slaked by
being placed in water just before it is desired for use. This milk
of lime should not be used until after the high temperature caused
by the violent chemical action has subsided. On account of the heat
involved and the high alkalinity in local portions, it is never safe to
apply crude lime to the juice without previously slaking it in water,
nor is it advisable to use a quantity of juice to mix this lime, as
is quite often practiced in these Islands, since in this case there
may be a loss of sucrose, with a resulting dark-colored product,
which will impair the color of the clarified juice. The following
chemical equation will express the reaction when this lime is slaked:
CaO (calcium oxide) + H2O (water)-->Ca(OH)2 (calcium hydroxide).
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