Before considering the methods to pursue and the reagents to use,
it is well to decide first upon the grade of sugar it is desirable to
make. If ordinary centrifugal sugar testing 96° is desired, it will
usually be practical to use only lime in the clarification, since in
these Islands cane reaches full maturity, and consequently the purity
of the normal juice will be quite high, sometimes as high as 90°
or 92° (apparent purity). If, however, it is desired to make a white
plantation sugar, or granulated sugar, it will be advisable to subject
the juice to an acidifying or bleaching treatment, as well as to the
lime treatment. Usually sulphurous acid is used for this purpose,
but sometimes phosphoric acid, or a form of it, is employed. It
is generally best to administer the acidifying agent before the
application of the lime, since this raises the acidity and permits a
larger amount of the lime to be used. However, this process is reversed
by some manufacturers, and very good results are often reported.
In the acidifying of any cane juice, care must be exercised that too
high an acidity is not reached, since acids have an inverting effect
upon sucrose, thus causing a noticeable loss. This of course depends
upon the degree of acidity carried, the temperature maintained,
and the methods followed during the time the juice remains acid.
When it is desired to make a high-grade crystal for granulated sugar,
the clarification must be more complete, and a water-white thick liquor
should result, without subsequent treatment by bleaching agents and
other chemicals, except the neutralizing of the slightly yellowish
tint, which will be mentioned later.
Reagents Used in Clarification.
There is a great variety of reagents at the command of the sugar
manufacturer, each of which has certain merits over others, and all
are valuable in their place when properly used. It will therefore
be the duty of the operator to select those which best meet his
individual conditions.
It is the purpose of this article to give a brief survey of the
more common reagents which, under certain conditions, may be used to
advantage in these Islands.
Lime.--This is perhaps one of the most common and most widely used
of all the reagents. Since the object in view is to increase the
purity of the juice, it is obvious that the purest rock obtainable
should be used in the preparation of the lime. Another reason why
a good lime should be employed, is that one of the main impurities
of the lime rock is magnesium, which, when mixed with cane juice,
becomes very troublesome in the incrusting of the evaporator tubes,
thus greatly lowering the coefficient of heat transmission.
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