By the wet method, the crude platinum is dissolved in aqua regia, with
excess of hydrochloric acid. Evaporation is continued until the whole of
the nitric acid is expelled. By addition of a solution of ammonium
chloride, the platinum is then precipitated as ammonium
platini-chloride. This precipitate is heated to redness, when chlorine
and ammonium chloride are given off, and spongy platinum remains. The
last is next granulated, after fusion by the oxy-hydrogen blowpipe in a
small lime furnace. Platinum obtained by this method may contain small
amounts of iridium, rhodium and palladium.
In the dry method, introduced by Delville and Debray, the crude platinum
is smelted with galena in a small reverberatory furnace. A portion of
the lead is reduced to the metallic state by the iron in the charge, and
forms a fusible alloy with the platinum. The osmiridium present settles
to the bottom of the furnace, and may thus be removed. Litharge is then
thrown in to form more alloy, and some glass to act as a flux. The alloy
is cupelled, and the residual platinum is then melted in a lime furnace
with the oxy-hydrogen flame. The platinum thus obtained often contains
iridium and rhodium.
A combination of these two methods is also sometimes employed[3] p. 403.
The electrolytic process of gold-refining was introduced to treat
platiniferous gold. In the gold chloride, or Wohlwill method, iridium
and osmiridium are insoluble, and remain with the anode slime. Platinum
and palladium, if nearly pure, are also insoluble, but when present
alloyed with gold and silver, pass into the solution and remain there.
In a hot bath it is stated that the platinum present should not exceed
50 gm. per litre. According to T. K. Rose, a cold bath containing only
20 gm. per litre causes a certain quantity of platinum to be deposited
with the gold[6].
H. F. Keller, in “Platinum, the Most Precious of Metals” (_Journal of
the Franklin Institute_, November 1912) deals fully with the extraction
and refining of platinum.
PLATINUM-REFINING AGENCIES
The following contains a list of the principal firms engaged in the
refining of platinum metals:
In England: Johnson, Matthey & Co., Ltd., Lees & Sanders, Warstone
Smelting Works, Sheffield Smelting Works, Johnson & Sons. (This is the
list of the Ministry of Munitions.)
In France: Legende et Cie., Compagnie Internationale du Platine, Lyon
Allemand, Lecht Lyonnais, Henrique Marrett, Bonnen, Hesse Fils.
In Germany: W. C. Heraeus, G. Siebert, F. Eisennad & Co.
In the United States: Baker & Co., American Platinum Works (N.T.),
Irvington Smelting and Refining Works, J. Bishop & Co., H. A. Wilson &
Co., Belais & Cohn, Kastenhuber & Lehrfeld, Roessler & Hasslacher
Chemical Co., Wildberg Bros., and others handling scrap.
According to Russian information about 25 per cent. of the Russian
output before the war was refined in Germany. In Russia there are
practically no platinum-refining facilities[7].
Public-domain text, read in full here on John Shaqi.
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