The Popular Science Monthly, July, 1900: Vol. 57, May, 1900 to October, 1900Various
Science
The Popular Science Monthly, July, 1900: Vol. 57, May, 1900 to October, 1900
Various
Science -- Periodicals; Technology -- Periodicals
Chemical changes at high temperatures have long been an object of
research, but it was not until the introduction of the electric furnace
that it was possible to command temperatures high enough to make
exhaustive studies. In the last few years several chemists, especially
Moissan, of Paris, and his pupils, have done systematic work with the
aid of the arc furnace. The furnace used in the laboratory for high
temperature work is a small and simple apparatus; Moissan’s furnace is
a block of quick lime a little longer and wider than a page of this
magazine and about three inches thick. A rectangular cavity is cut
on the upper surface of this block. A similar block forms the cover.
In opposite grooves between the top and bottom piece are placed the
carbons, such as are used in ordinary arc lights. The arc plays across
the cavity in such a manner that the substance to be heated is not
brought into the arc itself, which is vaporized carbon, but below it.
The cavity thus represents a tiny reverberatory furnace; the arc heats
the roof and sides to an intense heat, which is radiated on the open
dish or closed crucible or tube containing the substance heated. This
is the simplest form of laboratory furnace. Various modifications
are used, but in all the size is small and the arrangement simple. A
powerful arc plays in the smallest possible cavity with the object
of attaining the maximum of temperature, expense and duration of
material being secondary considerations. Lime and magnesia are the
best materials, because they are at the same time the most refractory
substances available and are poor conductors of heat. A furnace top
one and one half inches thick may be heated by so powerful an arc that
the melted quick lime drips from the inner surface, while the outer
surface is scarcely warm to the touch of the hand. Moissan has utilized
in these little furnaces currents of electricity of varied strength,
the lowest being that given by a four horse-power dynamo, the highest
that generated by three hundred horse power. The highest temperatures
obtained were about 3,500° centigrade (6,300° Fahrenheit), with the
heat constantly increasing; the limit to the obtainable temperature--as
far as the experimental evidence showed--was merely the lack of
any known substance refractory enough to bear the heat; for at the
temperature mentioned quick lime and magnesia not only melt but are
changed into gases, so that the furnace was filled with the vapors of
its own material.
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