The Popular Science Monthly, July, 1900: Vol. 57, May, 1900 to October, 1900Various
Science
The Popular Science Monthly, July, 1900: Vol. 57, May, 1900 to October, 1900
Various
Science -- Periodicals; Technology -- Periodicals
The effect of the heat on single substances is very interesting.
Refractory metals, such as iron, manganese, uranium, platinum, melt
rapidly and then become gaseous; the most refractory non-metallic
elements, silicon, boron, carbon, are also changed into the gaseous
form. Very refractory compounds are broken down into simpler ones.
Magnesium pyrophosphate yields phosphorus, magnesium oxide and oxygen.
Asbestos--a magnesium silicate--gives as chief product magnesium
silicide; the other substances formed being silicon, silicon dioxide
and a little magnesium oxide.
Such are the astounding changes wrought by simple heat upon those
substances which we are accustomed to regard as infusible. It must
be remembered that the range of temperature which chemists employ in
ordinary laboratory work is not very great and that the conditions of
work in the laboratory and of nature’s work on the earth’s surface at
the present day favor the formation of two classes of compounds--the
oxides and their hydrates. Although air is a mixture consisting mainly
of four parts of nitrogen and one of oxygen, atmospheric nitrogen is
generally inert at ordinary temperatures, and it is the oxygen of the
air which is the more important factor in the growth of living things
and in changes in lifeless matter. Water, a compound of oxygen and
hydrogen, is present everywhere, either in the liquid form or as vapor
in the air; even in the flame of the hottest fires there is water vapor
in abundance, since water is one of the chief products of combustion
of most forms of fuel. Is it a wonder that under such conditions we
find the earth’s crust to contain the elements chiefly compounded
with oxygen? Was this always so? Are we justified in supposing that
conditions may have prevailed--nay, must have prevailed--in former
times on the earth’s surface, which gave to other elements as important
or more important functions than to oxygen? The answer to these
questions must be sought in the results of the chemistry of high
temperatures.
First let us consider the conditions of existence of the omnipresent
water. Water begins to break down into its components, hydrogen and
oxygen, at 934° centigrade; at 2,500° centigrade (4,500° Fahrenheit)
the decomposition is complete. In other words, water vapor cannot exist
at temperatures above 2,500°, but the hydrogen and oxygen exist in the
free state.
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