The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
The formula given above works out at approximately 1 part strong acid to
2,000 parts of latex (of dry rubber content 1-1/2 lbs. per gallon). The
formula for using acetic acid with the same latex works out at about 1:
1,200. It will be apparent, therefore, that relatively sulphuric acid is a
more powerful coagulant than acetic acid. In terms of dry rubber obtained
from latex of the consistency indicated above--
1 lb. sulphuric acid will produce 300 lbs. dry rubber. 1 lb. acetic
acid will produce 180 lbs. dry rubber.
With both acids selling at the same rate, sulphuric acid would be more
economical in use; when its cost is less than that of acetic acid, which is
the normal condition, the economic advantage in favour of sulphuric acid is
augmented still further.
It may be found that the standard formula for sulphuric acid will not
always give a perfectly clear remaining serum, even though an attempt is
made daily to work to a uniform consistency for all latices. It is
inevitable that the manipulation of the latices should be slightly in error
on occasions, or that a small mistake might occur in preparing the solution
of acid. Hence a clear remaining serum after coagulation may be secured
less often than a slightly turbid serum. This is as it should be. The
minimum quantity of acid may be adjusted so closely as to give such
results. If a clear serum is obtained always, that should be an indication
of continual excess of coagulant. Naturally, if a milky serum is always
obtained, the reverse is the case.
As a last word on the subject, it may again be emphasised that the use of
sulphuric acid is not advised, except in an emergency; and that the
greatest possible care must be exercised in the observance of the strict
formula for use.
HYDROCHLORIC ACID, NITRIC ACID.--These mineral acids would prove more
expensive than sulphuric acid. In addition they are much more uncertain in
action. For example, the use of a certain excess of hydrochloric acid would
not hasten coagulation, but would prevent it. Above all their effect, in
excess, is deleterious to the rubber.
HYDROFLUORIC ACID.--This has a strong corrosive action on porcelain or
glass. Hence it has to be contained in bottles of gutta-percha or lead. It
is mentioned here merely because some years ago it found a use as a
coagulant, chiefly in Ceylon. It was sold in the form of a 10 per cent.
solution under the name of "Purub," and was the subject of a patent.
It is effective as a coagulant, and has also an anti-oxidant action, which
was its chief recommendation when cheap and harmless anti-oxidants were not
commonly known. It is comparatively expensive, and, as indicated above,
difficult to handle and store. In short, it has nothing to commend it, in
comparison with acetic or formic acids.
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