The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
(_b_) The efficiency of the apparatus.
(_c_) Condition of the timber as to moisture.
(_d_) The temperature employed, and rate of working.
(_e_) The point at which distillation ceases (_i.e._, the duration of
interval between commencement of heating and cessation of collection).
Samples received from estates for testing purposes were found to contain
equivalents varying from 2 per cent. to 10 per cent. of acetic acid.
They were all suitable coagulants when used in quantity calculated from the
discovered acidity, but produced rubber darker than ordinary when
air-dried. This effect was not of much importance in the preparation of
smoked sheets, but to produce a pale crepe it was necessary to employ
sodium bisulphite as an anti-oxidant.
This darkening in colour is to be ascribed to the presence of traces of
phenols,[24] which are stated to exert an effect upon the rubber during and
after vulcanisation.[25] This subject will be discussed in another section.
[24] Whitby, _Journal Soc. Chem. Industry_, vol. xxxv., No. 9, 1916.
[25] See also "Preparation and Vulcanisation of Plantation Rubber" (Eaton,
Grantham, and Day), Bulletin No. 27, F.M.S. Department of Agriculture,
April, 1918.
With this provision the crude pyroligneous acid which can be produced on
estates, could be employed as a coagulant until such time as the price of
glacial acetic acid was so low as to make the production of the crude acid
non-profitable. This point would be determined from a knowledge of the cost
of production per gallon, and the percentage of acetic acid per unit. For
example, if the cost of production (including cost of timber for
distillation, cost of fuel for heating the retort, cost of labour, etc.)
was 60 cents per gallon of crude acid containing 9 per cent. of acetic
acid, that would be equivalent approximately to buying glacial acetic acid
at $30 per demijohn of 44 lbs.
SMOKED WATER.--A weak solution of pyroligneous acid may also be obtained
by passing smoke through water. With this object in view, a machine was
designed by the Federated Engineering Company of Kuala Lumpur. In this the
principle of retorting was not employed. Smoke was produced by ordinary
combustion in a compartment of the apparatus, and was drawn through water
by the action of a high-speed fan worked by hand. A solution, equivalent in
effect to a 2 per cent. solution of acetic acid, could be obtained at a
comparatively cheaper cost than crude pyroligneous acid produced by dry
distillation as it was then being practised. This was chiefly because of
the wasteful methods of fuel combustion, in the latter process, in the
heating of the retort.
CHINESE VINEGAR.--This agent was found to be a satisfactory coagulant, and,
_a priori_, there is no reason why it should not be suitable, as it is
essentially a dilute solution of acetic acid.
The qualities sold were generally colourless, and were probably the result
of acetic fermentation of rice.
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