The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
Samples tested showed a varying content of acetic acid, ranging roughly
from 3 per cent. to 8 per cent.; but on this basis of valuation it was
found generally that the price bore no relation to the degree of
efficiency.
It was advanced not only that the vinegar was an efficient substitute for
glacial acetic acid, but that it was also cheaper. This latter claim was
proved to have no foundation in fact, even at the high price of acetic acid
prevailing during the period of stress. It is not likely, therefore, that
vinegar can displace acetic acid, except as an expedient.
SULPHUROUS ACID.--The anti-oxidant effect of sodium bisulphite and sodium
sulphite is due to the liberation of the gas, sulphur dioxide. This gas
dissolves easily in water, forming an acid solution called sulphurous acid.
This acid solution is an effective coagulant in fairly small quantity. Not
only so, but it produces, in addition, the anti-oxidant effect noted in the
employment of sodium bisulphite. It is thus possible to produce rubber
varying in shade of paleness by means of a single solution.
In the event of sulphurous acid being used, it would be necessary to
import cylinders of sulphur dioxide from which the solution could be
prepared in factories each day. There would be no insurmountable difficulty
in this, as it is only necessary to pass the gas through a series of closed
vessels containing water. Enough solution could be prepared at one time for
three or four days, but preferably the solutions should be as fresh as
possible. Altogether there would seem to be possibilities in the use of
sulphurous acid for preparing pale crepe rubbers, providing the cost is
within comparable limits with the commoner coagulants at present in use,
and that no adverse effect on the rubber can be shown to result. If the
cost did not exceed the combined cost of acetic acid and sodium bisulphite,
the employment of sulphurous acid solution might be worthy of
consideration. There is one drawback to the use of sulphurous acid
solution, and that lies in the proximity of the limits of the quantities
necessary for coagulation and that which is in excess, and prevents
coagulation. Thus, with ordinary field latex having about 20 per cent. dry
rubber content, the minimum necessary for coagulation per 100 c.c. of latex
is about 8 c.c. of a 1 per cent. solution. The maximum quantity possible
for use is about 15 c.c. of a 1 per cent, solution, so that great care
would have to be exercised in avoiding an excess of coagulant, otherwise
coagulation would be effectually prevented.
It is believed that the preparation of rubber by this method is the subject
of a patent secured by Messrs. Boake, Roberts, and Co., London.
SUGARS.--Coagulation may be effected by the addition of small quantities of
sugars.[26] These are assumed to be effective by fermentative conversion
into lactic and acetic acids. The presence of lactic acid is supposed to
have a twofold effect:
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