The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
Some estates make up a stock solution of 1 part acid to 20 of water, and
use this with success because of the fair amount of added water present in
the latex.
It must be understood that what is being referred to now is not the
absolute quantity necessary for coagulation, but the proportions--_i.e._,
the respective volumes of acid and water in the solution of acid made up
every day. That the strength of the acid solution, as well as the quantity
used, has an effect upon coagulation can be easily demonstrated in the
following way:
Take separate and equal lots of the same latex, and to each add the same
quantity of pure acid, but in each case diluted with varying quantities of
water. It will be found that coagulation is quickest where pure acid is
employed, and slowest where the acid is most dilute. It will also be found
that, providing the quantity of acid employed was sufficient for
coagulation, the best and most uniform coagulation is obtained from the use
of the most dilute acid, within limits. It will often be found that where
pure acid has been employed coagulation is local--_i.e._, we have lumpy
coagulation, and often a very milky remaining liquor. This is due to the
fact that, as coagulation is immediate upon the spot which is first touched
by the pure acid, a deal of the acid is enclosed within the rubber at that
spot, and hence other portions of the latex are deprived of acid. It is in
such cases that most air-bubbles are enclosed.
As the dilution of the acid solution is increased the mixing is more
thorough and uniform. Coagulation is slower, and air-bubbles can escape to
the surface.
METHOD OF MAKING STOCK SOLUTION.--Experiments have been repeatedly made in
the laboratory with acid solutions of varying dilution, from pure acid down
to 1 part of acid in 500 parts of water. While it has been found that a 1
in 5 solution can be used where the latex is very dilute (say, 1 part of
latex to 5 parts of water), and a 1 in 20 solution may be used in fairly
dilute latex (for crepe-making), it is undoubtedly a fact that for latex as
generally "standardised" on estates a much more dilute solution of acid
should be used--_e.g._, 1 in 100, or even 1 in 200, of water. It must be
borne in mind that the quantity of acid necessary for coagulation is not
changed, but merely the dilution. Let us take a concrete case to illustrate
the point:
On an estate at present the stock solution is made up by diluting 1
pint of acid with 20 pints of water, and 1 gallon of this is necessary
to coagulate 50 gallons of pure latex.
It is desired to use a stock solution of 1 pint of acid to 100 pints
of water. Evidently, therefore, 5 gallons of this stock solution
contain only the same quantity of pure acid as 1 gallon of the old
solution contained, and it will be necessary to add 5 gallons for
every 50 gallons of pure latex. Thus:
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