The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
MAKING A SOLUTION.--The making of a solution of the chemical would seem to
be a simple matter, but to judge by the ill-effects sometimes observed in
the dry rubber the simplicity of the operation appears to have been
overrated. Great care must be exercised in preparing the solution, and the
work should not be left to the few minutes preceding its actual
requirement; such has been found to be the case in several factories, so
that it is not surprising if the rubber is defective.
The powder should be added gradually to water with thorough stirring, which
should be continued for five minutes at least. Even then there may often be
seen at the bottom undissolved particles, sand, and other impurity. It is
necessary, therefore, in such cases to decant the solution through a piece
of cotton cloth before using. No solid particles should be allowed to enter
the latex.
ABUSE OF SODIUM BISULPHITE.--It is now generally recognised that the abuse
of sodium bisulphite, in the form of an excess, leads mainly to delay in
the period of drying and the production of an overpale rubber.[5] It is
probable that few estates, if any, now experience trouble due to this
non-observance of the rules and quantities laid down for use.
[5] "The Preparation of Plantation Rubber," Morgan, 1913, p. 74.
RESIDUAL TRACES OF SODIUM BISULPHITE.--The prolongation of the drying
period was attributed to the fact that traces of substances caused by the
decomposition of sodium bisulphite remained in the rubber if the rubber
were not sufficiently worked and washed on the rolls. These traces must
have been very minute, but they were sufficient to retard the progress of
drying. That much depended on the care exercised in washing is evident from
the fact that samples prepared with varying quantities of the chemical show
varying results on extraction. These samples were tested for the presence
of sulphates. Of the series tested that sample prepared with bisulphite in
the proportion of 1 part to 600 parts latex showed only a trace of sulphate
present; while the one prepared 1:2,400 gave an equal quantity.
Intermediate samples contained no trace of sulphate. On the whole,
therefore, the presence of sulphate in crepe rubber is adventitious, and
properly washed crepe prepared with moderate quantities of bisulphite may
be taken as free from any residual quantities. Meanwhile there cannot
possibly be any doubt of the advantages gained by the use of sodium
bisulphite, and it would not be very wide of the mark if the statement were
made that, in the event of this chemical being discarded, most contracts
for pale crepe could not be fulfilled.
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