The Principles of Biology, Volume 1 (of 2) — John Shaqi
The Principles of Biology, Volume 1 (of 2)Spencer, Herbert
Science
The Principles of Biology, Volume 1 (of 2)
Spencer, Herbert
Biology
Generalizing some of the facts which he gives, Professor Graham says:--"The
equivalent of a colloid appears to be always high, although the ratio
between the elements of the substance may be simple. Gummic acid, for
instance, may be represented by C^{12}H^{22}O^{11}; but, judging from the
small proportions of lime and potash which suffice to neutralize this acid,
the true numbers of its formula must be several times greater. It is
difficult to avoid associating the inertness of colloids with their high
equivalents, particularly where the high number appears to be attained by
the repetition of a small number. The inquiry suggests itself whether the
colloid molecule may not be constituted by the grouping together of a
number of smaller crystalloid molecules, and whether the basis of
colloidality may not really be this composite character of the molecule."
§ 7. A further contrast between colloids and crystalloids is equally
significant in its relations to vital phenomena. Professor Graham points
out that the marked differences in volatility displayed by different
bodies, are paralleled by differences in the rates of diffusion of
different bodies through liquids. As alcohol and ether at ordinary
temperatures, and various other substances at higher temperatures, diffuse
themselves in a gaseous form through the air; so, a substance in aqueous
solution, when placed in contact with a mass of water (in such way as to
avoid mixture by circulating currents) diffuses itself through this mass of
water. And just as there are various degrees of rapidity in evaporation, so
there are various degrees of rapidity in diffusion: "the range also in the
degree of diffusive mobility exhibited by different substances appears to
be as wide as the scale of vapour-tensions." This parallelism is what might
have been looked for; since the tendency to assume a gaseous state, and the
tendency to spread in solution through a liquid, are both consequences of
molecular mobility. It also turns out, as was to be expected, that
diffusibility, like volatility, has, other things equal, a relation to
molecular weight--other things equal, we must say, because molecular
mobility must, as pointed out in § 5, be affected by other properties of
atoms, besides their inertia. Thus the substance most rapidly diffused of
any on which Professor Graham experimented, was hydrochloric acid--a
compound which is of low molecular weight, is gaseous save under a pressure
of forty atmospheres, and ordinarily exists as a liquid, only in
combination with water. Again, "hydrate of potash may be said to possess
double the velocity of diffusion of sulphate of potash, and sulphate of
potash again double the velocity of sugar, alcohol, and sulphate of
magnesia,"--differences which have a general correspondence with
differences in the massiveness of their molecules.
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