The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
not crystallise are _colloids_, that is, resemble glue, and penetrate
through a membrane slowly, and form jellies; that is, occur in insoluble
forms,[18] as will be explained in speaking of silica.
[17] The researches of Graham, Fick, Nernst, and others showed that
the quantity of a dissolved substance which is transmitted
(rises) from one stratum of liquid to another in a vertical
cylindrical vessel is not only proportional to the time and to
the sectional area of the cylinder, but also to the amount and
nature of the substance dissolved in a stratum of liquid, so that
each substance has its corresponding co-efficient of diffusion.
The cause of the diffusion of solutions must be considered
as essentially the same as the cause of the diffusion of
gases--that is, as dependent on motions which are proper to their
molecules; but here most probably those purely chemical, although
feebly-developed, forces, which incline the substances dissolved
to the formation of definite compounds, also play their part.
[18] [Illustration: FIG. 15.--Dialyser. Apparatus for the separation
of substances which pass through a membrane from those which do
not. Description in text.]
The rate of diffusion--like the rate of transmission--through
membranes, or _dialysis_ (which plays an important part in the
vital processes of organisms and also in technical processes),
presents, according to Graham's researches, a sharply defined
change in passing from such crystallisable substances as the
majority of salts and acids to substances which are capable
of giving jellies (gum, gelatin, &c.) The former diffuse
into solutions and pass through membranes much more rapidly
than the latter, and Graham therefore distinguishes between
_crystalloids_, which diffuse rapidly, and _colloids_, which
diffuse slowly. On breaking solid colloids into pieces, a total
absence of cleavage is remarked. The fracture of such substances
is like that of glue or glass. It is termed a 'conchoidal'
fracture. Almost all the substances of which animal and vegetable
bodies consist are colloids, and this is, at all events, partly
the reason why animals and plants have such varied forms,
which have no resemblance to the crystalline forms of the
majority of mineral substances. The colloid solid substances in
organisms--that is, in animals and plants--almost always contain
water, and take most peculiar forms, of networks, of granules,
of hairs, of mucous, shapeless masses, &c., which are quite
different from the forms taken by crystalline substances. When
colloids separate out from solutions, or from a molten state,
they present a form which is similar to that of the liquid from
which they were formed.
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