The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Glass may he taken as the best example of
this. Colloids are distinguishable from crystalloids, not only
by the absence of crystalline form, but by many other properties
which admit of clearly distinguishing both these classes of
solids, as Graham showed. Nearly all colloids are capable of
passing, under certain circumstances, from a soluble into an
insoluble state. The best example is shown by white of eggs
(albumin) in the raw and soluble form, and in the hard-boiled
and insoluble form. The majority of colloids, on passing into
an insoluble form in the presence of water, give substances
having a gelatinous appearance, which is familiar to every one
in starch, solidified glue, jelly, &c. Thus gelatin, or common
carpenter's glue, when soaked in water, swells up into an
insoluble jelly. If this jelly be heated, it melts, and is then
soluble in water, but on cooling it again forms a jelly which
is insoluble in water. One of the properties which distinguish
colloids from crystalloids is that the former pass very slowly
through a membrane, whilst the latter penetrate very rapidly.
This may be shown by taking a cylinder, open at both ends, and
by covering its lower end with a bladder or with vegetable
parchment (unsized paper immersed for two or three minutes in a
mixture of sulphuric acid and half its volume of water, and then
washed), or any other membranous substance (all such substances
are themselves colloids in an insoluble form). The membrane must
be firmly tied to the cylinder, so as not to leave any opening.
Such an apparatus is called a _dialyser_ (fig. 15), and the
process of separation of crystalloids from colloids by means of
such a membrane is termed _dialysis_. An aqueous solution of a
crystalloid or colloid, or a mixture of both, is poured into the
dialyser, which is then placed in a vessel containing water, so
that the bottom of the membrane is covered with water. Then,
after a certain period of time, the crystalloid passes through
the membrane, whilst the colloid, if it does pass through at all,
does so at an incomparably slower rate. The crystalloid naturally
passes through into the water until the solution attains the same
strength on both sides of the membrane. By replacing the outside
water with fresh water, a fresh quantity of the crystalloid may
be separated from the dialyser. While a crystalloid is passing
through the membrane, a colloid remains almost entirely in the
dialyser, and therefore a mixed solution of these two kinds of
substances may be separated from each other by a dialyser. The
study of the properties of colloids, and of the phenomena of
their passage through membranes, should elucidate much respecting
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