The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
gravity increases, although on further diluting with water it
again falls. Moreover (Mendeléeff, _The Investigation of Aqueous
Solutions from their Specific Gravities_, 1887), the increase
in specific gravity (_ds_), varies in all well-known solutions
with the proportion of the substance dissolved (_dp_), and this
dependence can be expressed by a formula (_ds_/_dp_ = A + B_p_)
between the limits of definite compounds whose existence in
solutions must be admitted, and this is in complete accordance
with the dissociation hypothesis. Thus, for instance, from
H_{2}SO_{4} to H_{2}SO_{4} + H_{2}O (both these substances exist
as definite compounds in a free state), the fraction _ds_/_dp_
= 0·0729-0·000749_p_ (where _p_ is the percentage amount of
H_{2}SO_{4}). For alcohol C_{2}H_{6}O, whose aqueous solutions
have been more accurately investigated than all others, the
definite compound C_{2}H_{6}O + 3H_{2}O, and others must be
acknowledged in its solutions.
The two aspects of solution above mentioned, and the hypotheses
which have as yet been applied to the examination of solutions,
although they have somewhat different starting points, will
doubtless in time lead to a general theory of solutions,
because the same common laws govern both physical and chemical
phenomena, inasmuch as the properties and motions of molecules,
which determine physical properties, depend on the motions and
properties of atoms, which determine chemical reactions. For
details of the questions dealing with theories of solution,
recourse must now be had to special memoirs and to works on
theoretical (physical) chemistry; for this subject forms one of
special interest at the present epoch of the development of our
science. In working out chiefly the chemical side of solutions, I
consider it to be necessary to reconcile the two aspects of the
question; this seems to me to be all the more possible, as the
physical side is limited to dilute solutions only, whilst the
chemical side deals mainly with strong solutions.
In the consideration of the process of solution, besides the conception
of diffusion, another fundamental conception is necessary--namely, that
of the _saturation of solutions_.
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