The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Just as moist air may be diluted with any desired quantity of dry air,
so also an indefinitely large quantity of a liquid solvent may be
taken, and yet a uniform solution will be obtained. But more than a
definite quantity of aqueous vapour cannot be introduced into a certain
volume of air at a certain temperature. The excess above the point of
saturation will remain in the liquid state.[20] The relation between
water and substances dissolved in it is similar. More than a definite
quantity of a substance cannot, at a certain temperature, dissolve in
a given quantity of water; the excess does not unite with the water.
Just as air or a gas becomes saturated with vapour, so water becomes
saturated with a substance dissolved in it. If an excess of a substance
be added to water which is already saturated with it, it will remain in
its original state, and will not diffuse through the water. The quantity
of a substance (either by volume with gases, or by weight with solids
and liquids) which is capable of saturating 100 parts of water is called
the _co-efficient of solubility_ or the _solubility_. In 100 grams of
water at 15°, there can be dissolved not more than 35·86 grams of
common salt. Consequently, its solubility at 15° is equal to 35·86.[21]
It is most important to turn attention to the _existence of the solid
insoluble substances of nature_, because on them depends the shape
of the substances of the earth's surface, and of plants and animals.
There is so much water on the earth's surface, that were the surface of
substances formed of soluble matters it would constantly change, and
however substantial their forms might be, mountains, river banks and sea
shores, plants and animals, or the habitations and coverings of men,
could not exist for any length of time.[22]
[20] A system of (chemically or physically) re-acting substances in
different states of aggregation--for instance, some solid, others
liquid or gaseous--is termed a heterogeneous system. Up to now it
is only systems of this kind which can be subjected to detailed
examination in the sense of the mechanical theory of matter.
Solutions (_i.e._ unsaturated ones) form fluid homogeneous
systems, which at the present time can only be investigated with
difficulty.
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