The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[21] The solubility, or co-efficient of solubility, of a substance is
determined by various methods. Either a solution is expressly
prepared with a clear excess of the soluble substance and
saturated at a given temperature, and the quantity of water and
of the substance dissolved in it determined by evaporation,
desiccation, or other means; or else, as is done with gases,
definite quantities of water and of the soluble substance are
taken and the amount remaining undissolved is determined.
[Illustration: FIG. 16.--Bunsen's absorptiometer. Apparatus for
determining the solubility of gases in liquids.]
The solubility of a gas in water is determined by means of an
apparatus called an _absorptiometer_ (fig. 16). It consists of an
iron stand _f_, on which an india-rubber ring rests. A wide
glass tube is placed on this ring, and is pressed down on it by
the ring _h_ and the screws _i i_. The tube is thus firmly fixed
on the stand. A cock _r_, communicating with a funnel _r_, passes
into the lower part of the stand. Mercury can be poured into the
wide tube through this funnel, which is therefore made of steel,
as copper would be affected by the mercury. The upper ring _h_
is furnished with a cover _p_, which can be firmly pressed down
on to the wide tube, and hermetically closes it by means of an
india-rubber ring. The tube _r r_ can be raised at will, and
so by pouring mercury into the funnel the height of the column
of mercury, which produces pressure inside the apparatus, can
be increased. The pressure can also be diminished at will, by
letting mercury out through the cock _r_. A graduated tube _e_,
containing the gas and liquid to be experimented on, is placed
inside the wide tube. This tube is graduated in millimetres
for determining the pressure, and it is calibrated for volume,
so that the number of volumes occupied by the gas and liquid
dissolving it can be easily calculated. This tube can also be
easily removed from the apparatus. The lower portion of this
tube when removed from the apparatus is shown to the right of
the figure. It will be observed that its lower end is furnished
with a male screw _b_, fitting in a nut _a_. The lower surface of
the nut _a_ is covered with india-rubber, so that on screwing up
the tube its lower end presses upon the india-rubber, and thus
hermetically closes the whole tube, for its upper end is fused
up. The nut _a_ is furnished with arms _c c_, and in the stand
_f_ there are corresponding spaces, so that when the screwed-up
internal tube is fixed into stand _f_, the arms _c c_ fix into
these spaces cut in _f_. This enables the internal tube to be
fixed on to the stand _f_. When the internal tube is fixed in the
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