The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In the case of limited solution of liquids in liquids, _the
difference between the solvent and the substance dissolved_ is
clearly seen. The former (that is, the solvent) may be added in
an unlimited quantity, and yet the solution obtained will always
be uniform, whilst only a definite saturating proportion of the
substance dissolved can be taken, We will take water and common
(sulphuric) ether. On shaking the ether with the water, it will
be remarked that a portion of it dissolves in the water. If the
ether be taken in such a quantity that it saturates the water
and a portion of it remains undissolved, then this remaining
portion will act as a solvent, and water will diffuse through it
and also form a saturated solution of water in the ether taken.
Thus two saturated solutions will be obtained. One solution
will contain ether dissolved in water, and the other solution
will contain water dissolved in ether. These two solutions will
arrange themselves in two layers, according to their density;
the ethereal solution of water will be on the top. If the upper
ethereal solution be poured off from the aqueous solution,
any quantity of ether may be added to it; this shows that the
dissolving substance is ether. If water be added to it, it is
no longer dissolved in it; this shows that water saturates the
ether--here water is the substance dissolved. If we act in the
same manner with the lower layer, we shall find that water is the
solvent and ether the substance dissolved. By taking different
amounts of ether and water, the degree of solubility of ether in
water, and of water in ether, may be easily determined. Water
approximately dissolves 1/10 of its volume of ether, and ether
dissolves a very small quantity of water. Let us now imagine that
the liquid poured in dissolves a considerable amount of water,
and that water dissolves a considerable amount of the liquid. Two
layers could not be formed, because the saturated solutions would
resemble each other, and therefore they would intermix in all
proportions. This is, consequently, a case of a phenomenon where
two liquids present considerable co-efficients of solubility
in each other, but where it is impossible to say what these
co-efficients are, because it is impossible to obtain a saturated
solution.
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