The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Sometimes a substance is so slightly soluble that it may be
considered as insoluble. Many such substances are met with both
in solids and liquids, and such a gas as oxygen, although it
does dissolve, does so in so small a proportion by weight that
it might be considered as zero did not the solubility of even
so little oxygen play an important part in nature (as in the
respiration of fishes) and were not an infinitesimal quantity
of a gas by weight so easily measured by volume. The sign [oo],
which stands on a line with sulphuric acid in the above table,
indicates that it intermixes with water in all proportions.
There are many such cases among liquids, and everybody knows,
for instance, that spirit (absolute alcohol) can be mixed in any
proportion with water.
[22] Just as the existence must he admitted of substances which are
completely undecomposable (chemically) at the ordinary
temperature--and of substances which are entirely non-volatile
at such a temperature (as wood and gold), although capable
of decomposing (wood) or volatilising (gold) at a higher
temperature--so also the existence must be admitted of substances
which are totally insoluble in water without some degree of
change in their state. Although mercury is partially volatile at
the ordinary temperature, there is no reason to think that it
and other metals are soluble in water, alcohol, or other similar
liquids. However, mercury forms solutions, as it dissolves
other metals. On the other hand, there are many substances
found in nature which are so very slightly soluble in water,
that in ordinary practice they may be considered as insoluble
(for example, barium sulphate). For the comprehension of that
general plan according to which a change of state of substances
(combined or dissolved, solid, liquid, or gaseous) takes place,
it is very important to make a distinction at this boundary
line (on approaching zero of decomposition, volatility, or
solubility) between an insignificant amount and zero, but the
present methods of research and the data at our disposal at the
present time only just touch such questions (by studying the
electrical conductivity of dilute solutions and the development
of micro-organisms in them). It must be remarked, besides, that
water in a number of cases does not dissolve a substance as
such, but acts on it chemically and forms a soluble substance.
Thus glass and many rocks, especially if taken as powder, are
chemically changed by water, but are not directly soluble in it.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account