The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Substances which are easily soluble in water bear a certain resemblance
to it. Thus sugar and salt in many of their superficial features remind
one of ice. Metals, which are not soluble in water, have no points in
common with it, whilst on the other hand they dissolve each other in
a molten state, forming alloys, just as oily substances dissolve each
other; for example, tallow is soluble in petroleum and in olive oil,
although they are all insoluble in water. From this it is evident that
the _analogy of substances forming a solution_ plays an important part,
and as aqueous and all other solutions are liquids, there is good reason
to believe that in the process of solution solid and gaseous substances
change in a physical sense, passing into a liquid state. These
considerations elucidate many points of solution--as, for instance, the
variation of the co-efficient of solubility with the temperature and the
evolution or absorption of heat in the formation of solutions.
The solubility--that is, the quantity of a substance necessary for
saturation--_varies with the temperature_, and, further, with an
increase in temperature the solubility of solid substances generally
increases, and that of gases decreases; this might be expected, as solid
substances by heating, and gases by cooling, approach to a liquid or
dissolved state.[23] A graphic method is often employed to express the
variation of solubility with temperature. On the axis of abscissæ or on
a horizontal line, temperatures are marked out and perpendiculars are
raised corresponding with each temperature, whose length is determined
by the solubility of the salt at that temperature--expressing, for
instance, one part by weight of a salt in 100 parts of water by one
unit of length, such as a millimetre. By joining the summits of the
perpendiculars, a curve is obtained which expresses the degree of
solubility at different temperatures. For solids, the curve is generally
an ascending one--_i.e._ recedes from the horizontal line with the
rise in temperature. These curves clearly show by their inclination
the degree of rapidity of increase in solubility with the temperature.
Having determined several points of a curve--that is, having made a
determination of the solubility for several temperatures--the solubility
at intermediary temperatures may be determined from the form of the
curve so obtained; in this way the empirical law of solubility may be
examined.[24] The results of research have shown that the solubility of
certain salts--as, for example, common table salt--varies comparatively
little with the temperature; whilst for other substances the solubility
increases by equal amounts for equal increments of temperature. Thus,
for example, for the saturation of 100 parts of water by potassium
chloride there is required at 0°, 29·2 parts, at 20°, 34·7, at 40°,
40·2, at 60°, 45·7; and so on, for every 10° the solubility increases
by 2·75 parts by weight of the salt. Therefore the solubility of the
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