The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
potassium chloride in water may be expressed by a direct equation: _a_ =
29·2 + 0·275_t_, where _a_ represents the solubility at _t_°. For other
salts, more complicated equations are required. For example, for nitre:
_a_ = 13·3 + 0·574_t_ + 0·01717_t_^2 + 0·0000036_t_^3, which shows that
when _t_ = 0° _a_ = 13·3, when _t_ = 10° _a_ = 20·8, and when _t_ = 100°
_a_ = 246·0.
[23] Beilby (1883) experimented on paraffin, and found that one litre
of solid paraffin at 21° weighed 874 grams, and when liquid, at
its melting-point 38°, 783 grams, at 49°, 775 grams, and at 60°,
767 grams, from which the weight of a litre of liquefied paraffin
would be 795·4 grams at 21° if it could remain liquid at that
temperature. By dissolving solid paraffin in lubricating oil at
21° Beilby found that 795·6 grams occupy one cubic decimetre,
from which he concluded that the solution contained liquefied
paraffin.
[24] Gay-Lussac was the first to have recourse to such a graphic
method of expressing solubility, and he considered, in accordance
with the general opinion, that by joining up the summits of the
ordinates in one harmonious curve it is possible to express the
entire change of solubility with the temperature. Now, there are
many reasons for doubting the accuracy of such an admission, for
there are undoubtedly critical points in curves of solubility
(for example, of sodium sulphate, as shown further on), and it
may be that definite compounds of dissolved substances with
water, in decomposing within known limits of temperature, give
critical points more often than would be imagined; it may even
be, indeed, that instead of a continuous curve, solubility should
be expressed--if not always, then not unfrequently--by straight
or broken lines. According to Ditte, the solubility of sodium
nitrate, NaNO_{3}, is expressed by the following figures per 100
parts of water:--
0° 4° 10° 15° 21° 29° 36° 51° 68°
66·7 71·0 76·3 80·6 85·7 92·9 99·4 113·6 125·1
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