The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[26] The cooling effect produced in the solution of solids (and also in
the expansion of gases and in evaporation) is applied to the
_production of low temperatures_. Ammonium nitrate is very often
used for this purpose; in dissolving in water it absorbs 77 units
of heat per each part by weight. On evaporating the solution thus
formed, the solid salt is re-obtained. The application of the
various _freezing mixtures_ is based on the same principle. Snow
or broken ice frequently enters into the composition of these
_mixtures_, advantage being taken of its latent heat of fusion in
order to obtain the lowest possible temperature (without altering
the pressure or employing heat, as in other methods of obtaining
a low temperature). For laboratory work recourse is most often
had to a mixture of three parts of snow and one part of common
salt, which causes the temperature to fall from 0° to -21° C.
Potassium thiocyanate, KCNS, mixed with water (3/4 by weight of
the salt) gives a still lower temperature. By mixing ten parts of
crystallised calcium chloride, CaCl_{2},6H_{2}O, with seven parts
of snow, the temperature may even fall from 0° to -55°.
[27] The heat which is evolved in solution, or even in the dilution of
solutions, is also sometimes made use of in practice. Thus
caustic soda (NaHO), in dissolving or on the addition of water to
a strong solution of it, evolves so much heat that it can replace
fuel. In a steam boiler, which has been previously heated to
the boiling point, another boiler is placed containing caustic
soda, and the exhaust steam is made to pass through the latter;
the formation of steam then goes on for a somewhat long period
of time without any other heating. Norton makes use of this for
smokeless street locomotives.
[28] [Illustration: FIG. 17.--Curves expressing the contraction,
quantity of heat, and rises of temperature produced by mixing
sulphuric acid with water. Percentage of H_{2}SO_{4} is given
along the axis of abscissae.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account