The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The temperatures obtained by mixing monohydrated sulphuric acid,
H_{2}SO_{4}, with different quantities of water, are shown on
the lowest curve in fig. 17, the relative proportions of both
substances being expressed in percentages by weight along the
horizontal axis. The greatest rise of temperature is 149°. It
corresponds with the greatest evolution of heat (given on the
middle curve) corresponding with a definite volume (100 c.c.)
of the solution produced. The top curve expresses the degree
of contraction, which also corresponds with 100 volumes of
the solution produced. The greatest contraction, as also the
greatest rise of temperature, corresponds with the formation of a
trihydrate, H_{2}SO_{4},2H_{2}O (= 73·1 p.c. H_{2}SO_{4}), which
very likely repeats itself in a similar form in other solutions,
although all the phenomena (of contraction, evolution of heat,
and rise of temperature) are very complex and are dependent
on many circumstances. One would think, however, judging from
the above examples, that all other influences are feebler in
their action than chemical attraction, especially when it is so
considerable as between sulphuric acid and water.
Solution is a reversible reaction; for, if the water be expelled from a
solution, the substance originally taken is obtained again. But it must
be borne in mind that the expulsion of the water taken for solution is
not always accomplished with equal facility, because water has different
degrees of chemical affinity for the substance dissolved. Thus, if a
solution of sulphuric acid, which mixes with water in all proportions,
be heated, it will be found that very different degrees of heat are
required to expel the water. When it is in a large excess, water is
given off at a temperature slightly above 100°, but if it be in but a
small proportion there is such an affinity between it and the sulphuric
acid that at 120°, 150°, 200°, and even at 300°, water is still retained
by the sulphuric acid. The bond between the remaining quantity of water
and the sulphuric acid is evidently stronger than the bond between the
sulphuric acid and the excess of water. The force acting in solutions
is consequently of different intensity, starting from so feeble an
attraction that the properties of water--as, for instance, its power
of evaporation--are but very little changed, and ending with cases of
strong attraction between the water and the substance dissolved in or
chemically combined with it. In consideration of the very important
significance of the phenomena, and of the cases of the breaking up of
solutions with separation of water or of the substance dissolved from
them, we shall further discuss them separately, after having acquainted
ourselves with certain peculiarities of the solution of gases and of
solid bodies.
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