The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
It will be remarked, for instance, from this table that whilst the
pressure increased 10 times, the solubility of ammonia only increased
4-1/2 times.
A number of examples of such cases of the absorption of gases by liquids
might be cited which do not in any way, even approximately, agree with
the laws of solubility. Thus, for instance, carbonic anhydride is
absorbed by a solution of caustic potash in water, and if sufficient
caustic potash be present it is not separated from the solution by
a decrease of pressure. This is a case of more intimate chemical
combination. A correlation less completely studied, but similar and
clearly chemical, appears in certain cases of the solution of gases in
water, and we shall afterwards find an example of this in the solution
of hydrogen iodide; but we will first stop to consider a remarkable
application of the law of Henry and Dalton[33] in the case of the
solution of a mixture of two gases, and this we must do all the more
because the phenomena which there take place cannot be foreseen without
a clear theoretical representation of the nature of gases.[34]
[33] The ratio between the pressure and the amount of gas dissolved
was discovered by Henry in 1805, and Dalton in 1807 pointed
out the adaptability of this law to cases of gaseous mixtures,
introducing the conception of partial pressures which is
absolutely necessary for a right comprehension of Dalton's law.
The conception of partial pressures essentially enters into
that of the diffusion of vapours in gases (footnote 1); for
the pressure of damp air is equal to the sum of the pressures
of dry air and of the aqueous vapour in it, and it is admitted
as a corollary to Dalton's law that evaporation in dry air
takes place as in a vacuum. It is, however, necessary to remark
that the volume of a mixture of two gases (or vapours) is only
approximately equal to the sum of the volumes of its constituents
(the same, naturally, also refers to their pressures)--that is to
say, in mixing gases a change of volume occurs, which, although
small, is quite apparent when carefully measured. For instance,
in 1888 Brown showed that on mixing various volumes of sulphurous
anhydride (SO_{2}) with carbonic anhydride (at equal pressures
of 760 mm. and equal temperatures) a decrease of pressure of
3·9 millimetres of mercury was observed. The possibility of a
chemical action in similar mixtures is evident from the fact that
equal volumes of sulphurous and carbonic anhydrides at -19° form,
according to Pictet's researches in 1888, a liquid which may be
regarded as an unstable chemical compound, or a solution similar
to that given when sulphurous anhydride and water combine to an
unstable chemical whole.
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