The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[34] The origin of the kinetic theory of gases now generally accepted,
according to which they are animated by a rapid progressive
motion, is very ancient (Bernouilli and others in the last
century had already developed a similar representation), but
it was only generally accepted after the mechanical theory of
heat had been established, and after the work of Krönig (1855),
and especially after its mathematical side had been worked out
by Clausius and Maxwell. The pressure, elasticity, diffusion,
and internal friction of gases, the laws of Boyle, Mariotte,
and of Gay-Lussac and Avogadro-Gerhardt are not only explained
(deduced) by the kinetic theory of gases, but also expressed
with perfect exactitude; thus, for example, the magnitude of
the internal friction of different gases was foretold with
exactitude by Maxwell, by applying the theory of probabilities
to the impact of gaseous particles. The kinetic theory of gases
must therefore be considered as one of the most brilliant
acquisitions of the latter half of the present century. The
velocity of the progressive motion of the particles of a gas, one
cubic centimetre of which weighs _d_ grams, is found, according
to the theory, to be equal to the square root of the product of
3_pDq_ divided by _d_, where _p_ is the pressure under which _d_
is determined expressed in centimetres of the mercury column,
_D_ the weight of a cubic centimetre of mercury in grams (_D_
= 13·59, _p_ = 76, consequently the normal pressure = 1,033
grams on a sq. cm.), and _g_ the acceleration of gravity in
centimetres (_g_ = 980·5, at the sea level and long. 45° = 981·92
at St. Petersburg; in general it varies with the longitude and
altitude of the locality). Therefore, at 0° the velocity of
hydrogen is 1,843, and of oxygen 461, metres per second. This
is the average velocity, and (according to Maxwell and others)
it is probable that the velocities of individual particles
are different; that is, they occur in, as it were, different
conditions of temperature, which it is very important to take
into consideration in investigating many phenomena proper to
matter. It is evident from the above determination of the
velocity of gases, that different gases at the same temperature
and pressure have average velocities, which are inversely
proportional to the square roots of their densities; this is also
shown by direct experiment on the flow of gases through a fine
orifice, or through a porous wall. This _dissimilar velocity of
flow_ for different gases is frequently taken advantage of in
chemical researches (see Chap. II. and also Chap. VII.) in order
to separate two gases having different densities and velocities.
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