The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
_The law of partial pressures_ is as follows:--The solubility of gases
in intermixture with each other does not depend on the influence of
the total pressure acting on the mixture, but on the influence of that
portion of the total pressure which is due to the volume of each given
gas in the mixture. Thus, for instance, if oxygen and carbonic anhydride
were mixed in equal volumes and exerted a pressure of 760 millimetres,
then water would dissolve so much of each of these gases as would be
dissolved if each separately exerted a pressure of half an atmosphere,
and in this case, at 0° one cubic centimetre of water would dissolve
0·02 cubic centimetre of oxygen and 0·90 cubic centimetre of carbonic
anhydride. If the pressure of a gaseous mixture equals _h_, and in _n_
volumes of the mixture there be _a_ volumes of a given gas, then its
solution will proceed as though this gas were dissolved under a pressure
(_h_ × _a_)/_n_. That portion of the pressure under influence of which
the solution proceeds is termed the 'partial' pressure.
In order to clearly understand the cause of the law of partial
pressures, an explanation must be given of the fundamental properties
of gases. Gases are elastic and disperse in all directions. We are led
from what we know of gases to the assumption that these fundamental
properties of gases are due to a rapid progressive motion, in all
directions, which is proper to their smallest particles (molecules).[35]
These molecules in impinging against an obstacle produce a pressure.
The greater the number of molecules impinging against an obstacle in
a given time, the greater the pressure. The pressure of a separate
gas or of a gaseous mixture depends on the sum of the pressures of
all the molecules, on the number of blows in a unit of time on a unit
of surface, and on the mass and velocity (or the _vis viva_) of the
impinging molecules. The nature of the different molecules is of no
account; the obstacle is acted on by a pressure due to the sum of their
_vis viva_. But, in a chemical action such as the solution of gases,
the nature of the impinging molecules plays, on the contrary, the
most important part. In impinging against a liquid, a portion of the
gas enters into the liquid itself, and is held by it so long as other
gaseous molecules impinge against the liquid--exert a pressure on it. As
regards the solubility of a given gas, for the number of blows it makes
on the surface of a liquid, it is immaterial whether other molecules
of gases impinge side by side with it or not. Hence, the solubility
of a given gas will be proportional, not to the total pressure of a
gaseous mixture, but to that portion of it which is due to the given
gas separately. Moreover, the saturation of a liquid by a gas depends
on the fact that the molecules of gases that have entered into a liquid
do not remain at rest in it, although they enter in a harmonious kind
of motion with the molecules of the liquid, and therefore they throw
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