The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
themselves off from the surface of the liquid (just like its vapour
if the liquid be volatile). If in a unit of time an equal number of
molecules penetrate into (leap into) a liquid and leave (or leap out
of) a liquid, it is saturated. It is a case of mobile equilibrium, and
not of rest. Therefore, if the pressure be diminished, the number of
molecules departing from the liquid will exceed the number of molecules
entering into the liquid, and a fresh state of mobile equilibrium only
takes place under a fresh equality of the number of molecules departing
from and entering into the liquid. In this manner the main features of
the solution are explained, and furthermore of that special (chemical)
attraction (penetration and harmonious motion) of a gas for a liquid,
which determines both the measure of solubility and the degree of
stability of the solution produced.
[35] Although the actual motion of gaseous molecules, which is accepted
by the kinetic theory of gases, cannot be seen, yet its existence
may be rendered evident by taking advantage of the difference in
the velocities undoubtedly belonging to different gases which
are of different densities under equal pressures. The molecules
of a light gas must move more rapidly than the molecules of
a heavier gas in order to produce the same pressure. Let us
take, therefore, two gases--hydrogen and air; the former is
14·4 times lighter than the latter, and hence the molecules of
hydrogen must move almost four times more quickly than air (more
exactly 3·8, according to the formula given in the preceding
footnote). Consequently, if a porous cylinder containing air is
introduced into an atmosphere of hydrogen, then in a given time
the volume of hydrogen which succeeds in entering the cylinder
will be greater than the volume of air leaving the cylinder, and
therefore the pressure inside the cylinder will rise until the
gaseous mixture (of air and hydrogen) attains an equal density
both inside and outside the cylinder. If now the experiment
be reversed and air surround the cylinder, and hydrogen be
inside the cylinder, then more gas will leave the cylinder than
enters it, and hence the pressure inside the cylinder will be
diminished. In these considerations we have replaced the idea of
the number of molecules by the idea of volumes. We shall learn
subsequently that equal volumes of different gases contain an
equal number of molecules (the law of Avogadro-Gerhardt), and
therefore instead of speaking of the number of molecules we can
speak of the number of volumes. If the cylinder be partially
immersed in water the rise and fall of the pressure can be
observed directly, and the experiment consequently rendered
self-evident.
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