The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The consequences of the law of partial pressures are exceedingly
numerous and important. All liquids in nature are in contact with the
atmosphere, which, as we shall afterwards see more fully, consists of
an intermixture of gases, chiefly four in number--oxygen, nitrogen,
carbonic anhydride, and aqueous vapour. 100 volumes of air contain,
approximately, 78 volumes of nitrogen, and about 21 volumes of oxygen;
the quantity of carbonic anhydride, by volume, does not exceed 0·05.
Under ordinary circumstances, the quantity of aqueous vapour is much
greater than this, but it varies of course with climatic conditions. We
conclude from these numbers that the solution of nitrogen in a liquid
in contact with the atmosphere will proceed under a partial pressure of
(78/100) × 760 mm. if the atmospheric pressure equal 760 mm.; similarly,
under a pressure of 600 mm. of mercury, the solution of oxygen will
proceed under a partial pressure of about 160 mm., and the solution of
carbonic anhydride only under the very small pressure of 0·4 mm. As,
however, the solubility of oxygen in water is twice that of nitrogen,
the ratio of O to N dissolved in water will be greater than the ratio in
air. It is easy to calculate what quantity of each of the gases will be
contained in water, and taking the simplest case we will calculate what
quantity of oxygen, nitrogen, and carbonic anhydride will be dissolved
from air having the above composition at 0° and 760 mm. pressure. Under
a pressure of 760 mm. 1 cubic centimetre of water dissolves 0·0203
cubic centimetre of nitrogen or under the partial pressure of 600 mm. it
will dissolve 0·0203 × 600/760, or 0·0160 cubic centimetre; of oxygen
0·0411 × 160/760, or 0·0086 cubic centimetre; of carbonic anhydride 1·8
× 0·4/760 or 0·00095 cubic centimetre: hence, 100 cubic centimetres
of water will contain at 0° altogether 2·55 cubic centimetres of
atmospheric gases, and 100 volumes of air dissolved in water will
contain about 62 p.c. of nitrogen, 34 p.c. of oxygen, and 4 p.c. of
carbonic anhydride. The water of rivers, wells, &c. usually contains
more carbonic anhydride. This proceeds from the oxidation of organic
substances falling into the water. The amount of oxygen, however,
dissolved in water appears to be actually about 1/3 the dissolved gases,
whilst air contains only 1/5 of it by volume.
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